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Publications and Scientific Papers

NanoScale Corporation’s Founder and Scientific Adviser, Dr. Ken Klabunde, as well as many of the company’s scientists are considered leaders in the field of “nano-chemistry”. The following represents a “sample” reference listing of their publications and scientific papers. For additional information Contact Us.

  1. Burton, D.J.; Herkes, F.E.; and Klabunde, K.J., "The Reaction of Trifluoromethyl Ketones and Trialkylphosphines," J. Amer. Chem. Soc., 88, 5042 (1966).
  2. Klabunde, K.J., and Burton, D.J., "The Synthesis of Amino-Substituted α, α,α-Trifluoroacetophenones," J. Org. Chem., 35, 1711 (1970).
  3. Klabunde, K.J., "A Study of the Photolytic Stabilities of Fluoroalkyl Iodides by Electron Spin Resonance Trapping Techniques and the Temperature Dependence of the Nitroxide Splitting Constants," J. Amer. Chem. Soc., 92, 2427 (1970).
  4. Janzen, E.G.; Knauer, B.R.; Gerlock, J.L.; and Klabunde, K.J., "On the Angular Dependence of β-Fluorine Electron Spin Resonance Hyperfine Coupling in Fluoro-Substituted Nitroxide Radicals," J. Phys. Chem., 74, 2037 (1970).
  5. Skell, P.S.; Klabunde, K.J.; and Plonka, J.H., "Deoxygenation of Oxetanes by Carbon Atoms.  On the Intermediacy of Trimethylene," Chem. Commun., 1109 (1970).
  6. Klabunde, K.J., and Skell, P.S., "The Chemistry of Atomic Carbon.  Desulfurization," J. Amer. Chem. Soc., 93, 3807 (1971).
  7. Klabunde, K.J., and Burton, D.J., “The Acidities of Polyfluorinated Hydrocarbons.  I. Aryl Substituted 2-Hydro-2-Phenyl-Hexafluoropropanes.  Intermediate Carbanion Stability and Geometry,” J. Amer. Chem. Soc., 94, 820 (1972).
  8. Klabunde, K.J., and Burton, D.J., “The Acidities of Polyfluorinated Hydrocarbons.  II. Hexafluoropropanes, Trifluoroethanes, and Haloforms.  Intermediate Carbanion Stability and Geometry,” J. Amer. Chem. Soc., 94, 5985 (1972).
  9. Klabunde, K.J., and  Key, M.S., “Metal Atoms Reactions with Fluorocarbons.  I. Non-Solvated Fluoroorgano Zinc Compounds,” J. Amer. Chem. Soc., 94, 999 (1972).
  10. Klabunde, K.J.; Low, J.Y.F.; and Key, M.S., “Metal Atoms Reactions with Fluorocarbons.  II. Defluorination by Calcium Atoms,” J. Fluorine Chem.,  2(2), 207 (1972).
  11. Skell, P.S.; Fagone, F.A.; and Klabunde, K.J., “Reactions of Diatomic Carbon with Alkanes and Ethers.  Trapping Alkyl Carbenes by Vinylidene,” J. Amer. Chem. Soc., 94, 7862 (1972).
  12. Skell, P.S.; Klabunde, K.J.; Plonka, J.H.; Roberts, J.S.; and Williams- Smith, D.L., "Deoxygenation and Desulfurization of Cyclic Ethers and Thioethers by Carbon Atoms.  Intermediates with Excess Energy in a Low- Temperature Matrix," J. Amer. Chem. Soc., 95, 1547 (1973).
  13. Klabunde, K.J., and Low, J.Y.F., "Metal Atom Reactions with Fluorocarbons.  III. Oxidative Insertion of Palladium Atoms Into Aryl Carbon-Halogen Bonds," J. Organometal. Chem., 51, C33 (1973).
  14. Klabunde, K.J.; Low, J.Y.F.; and Efner, H.F., "Synthesis of Bis- (triethylphosphine) Organometallic Complexes Employing Nickel and Palladium Atoms as Synthetic Reagents," J. Amer. Chem. Soc., 96, 1984 (1974).
  15. Klabunde, K.J., and Efner, H.F., "Metal Atom Reactions with Fluorocarbons.  IV. Nickel (O) and Other Transition Metal Zero Valent Complexes with Hexafluorobenzene and Benzene," J. Fluorine Chem., 4, 115 (1974).
  16. Klabunde, K.J.; White, C.M.; and Efner, H.F., "Carbon Monosulfide Used in Synthesis of Halosulfur Compounds," Inorganic Chemistry, 13, 1778 (1974).
  17. Klabunde, K.J.; Efner, H.F.; Satek, L.; and Donley, W., "Preparation of an Extremely Active Magnesium Slurry for Grignard Preparations by Metal Atom- Solvent Cocondensations," J. Organometallic Chem., 71, 309 (1974).
  18. Klabunde, K.J., and Low, J.Y.F., "Synthesis Employing Oxidative Insertion of Palladium Atoms into Aryl, Alkyl, and Acyl Carbon-Halogen Bonds.  Properties of and Phosphine Trapping of the Non-Ligand Stabilized RPdX and  RCOPdX Intermediates," J. Amer. Chem. Soc., 96, 7674 (1974).
  19. Klabunde, K.J., Review of "Inorganic Chemistry of the Transition Elements II (B.F.G. Johnson)," J. Amer. Chem. Soc., 96, 5298 (1974).
  20. Roberts, J.S., and Klabunde, K.J., "Synthesis of Benzylpalladium Chloride Employing Palladium Atoms," J. Organomet. Chem., 85, C13 (1975).
  21. Klabunde, K.J. and Efner, H.F., "Metal Atom Reactions with Fluorocarbons.  VI. Complexes of Halogenated Benzenes with Vanadium (O) and Chromium (O).  Effects of Strongly Withdrawing Substituents, Particularly Trifluoromethyl  Groups," Inorg. Chem., 14, 789 (1975).
  22. Klabunde, K.J., "Metal Vapors as Reagents in Organometallic Synthesis," Chemical Technology, 6, 624 (1975).
  23. Klabunde, K.J., "Organic Chemistry of Metal Vapors," Acc. Chem. Res., 8, 393 (1975).
  24. Low, J.Y.F.; Klabunde, K.J.; Stenberg, V.I.; Woolsey, N.; Baltisberger, R.; Govek, M.; Wolf, M.; Rice, J.; Switzer, S.; and Mannering, M., "Catalytic Hydrogenation of Solvent Refined Lignite to Liquid Fuels," ACS Fuel Division Preprints, 20(1), 122 (1975).
  25. Klabunde, K.J., "Metal Atom Reactions with Fluorocarbons," Angew. Chemie., 87, 309 (1975); Int. Ed. 14(5), 287 (1975).
  26. Klabunde, K.J., "Vapors of the Elements as Chemical Reagents," American Laboratory, November 7, 35-8, 40-4, (1975).
  27. Klabunde, K.J., "Reactions of Metal Atoms with Fluorocarbons," New Syn. Methods, 3, 135 (1975).
  28. Klabunde, K.J., "Metal Atom Reactions with Fluorocarbons. VIII. F-Alkyl Iodides with Silver Vapors with Formation of F-Alkylsilver Compounds," J.Fluorine Chem., 7, 95 (1976).
  29. Klabunde, K.J.; Efner, H.F.; Murdock, T.O.; and Roppel, R., "Solvated Nickel Atoms and Their Free Cluster Formation in Organic Media," J. Amer. Chem. Soc., 98, 1021 (1976).
  30. Murdock, T.O. and Klabunde, K.J., 'Preparation and Reactions of Highly Active Cadmium and Zinc Slurries by Metal Atom-Solvent Co-condensations,"  J. Organic Chem., 41, 1076 (1976).
  31. Anderson, B.B.; Behrens, C.L.; Radonovich, L.J.; and Klabunde, K.J., "Metal Atom Synthesis of η6-Toluene bis (F-phenyl) Cobalt(II), A New Type of π-Arene Complex.  X-Ray Structure Determination," J. Amer. Chem. Soc., 98, 5390 (1976).
  32. Woolsey, N.F.; Baltisberger, R.J.; Klabunde, K.J.; Stenberg, V.I.; and Kaba, R., "Characterization of Solvent Refined Lignite and Solvent Refined Coal Structural Features.  Computerized Methodology Development," ACS Fuel Division Preprints, 21(7), 33 (1976) (Klabunde was invited lecturer on this topic for Storch Award Symposium).
  33. Wescott, L.D.; Williford, C.; Parks, F.; Dowling, M.; Sublett, S.; and Klabunde, K.J., "Reactions of Magnesium Vapor with Cycloheptanone," J. Amer. Chem. Soc., 98, 7853 (1976).
  34. Radonovich, L.; Zuerner, C.; Efner, H.F.; and Klabunde, K.J., "Stereochemistry of bis-(1,4-difluorobenzene) Vanadium (O) [p-C6H4F2)2V]," Inorg. Chem., 15(12), 2976 (1976).
  35. Low, J.Y.F.; Klabunde, K.J.; Woolsey, N.F.; Baltisberger, R.; Govek, M.; and Stenberg, V.I., "Catalytic Hydrogenation of Solvent Refined Lignite to Liquid Fuels," Energy Sources, 3(1), 19 (1976).
  36. Roberts, J.S. and Klabunde, K.J., "The Direct Synthesis of η3-ArCH2PdCl Compounds by Oxidative Addition of ArCH2-Chlorine Bonds to Palladium Atoms," J. Amer. Chem. Soc., 99, 2509 (1977).
  37. Klabunde, K.J., "Organic Chemistry of Metal Vapors: π-Complexes to Solvated Metal to Metal Clusters," Annals of New York Acad. Sci., 295, 83 (1977).
  38. Klabunde, K.J.; Jones, D.; Ralston, D.; Tanabe, K.; Govek, M.; Stenberg, V.I.; Woolsey, N; and Baltisberger, R., Proceedings of Lignite Symposium, GFERC, IC-77-1, May (1977), "Production of Clean Liquid Fuels from Lignite  Employing Novel Low Surface Catalysts and Commercial Catalysts."
  39. Klabunde, K.J., "Metal Atom Research Spawns New Catalysts, Chem. and Eng. News, page 23, January 24, 1977.
  40. Klabunde, K.J. and Roberts, J.S., "A Mechanistic Investigation of the Oxidative Addition of Alkyl Halides to Palladium Atoms," J. Organomet.    Chem., 137, 113 (1977).
  41. Ralston, D.; Govek, M.; Graf, C.; Jones, D.S.; Tanabe, K.; Klabunde, K.J.; Woolsey, N.F.; Baltisberger, R.J.; and Stenberg, V.I., "Catalytic Activities and Selectivities of MoO3-NiSO4 Supported on Various Oxides for Hydrocracking of Solvent Refined Lignite; Novel Low Surface Area Active Catalysts," Fuel Processing Tech., 1, 143 (1977).
  42. Baltisberger, R.J.; Klabunde, K.J.; Stenberg, V.I.; Woolsey, N.F.; Saito, K.; and Sukalski, W., "Comparison of Solvent Refined Lignite with Solvent Refined Bituminous Coals," ACS Fuel Div. Preprints, 22(5), 84 (1977).
  43. Jones, D.; Baltisberger, R.J.; Klabunde, K.J.; Woolsey, N.F.; and Stenberg, V.I., "Carbon Monoxide-Hydrogen-Water.  Reduction of Benzophenone, Diphenylcarbinol, Diphenylmethane," J. Org. Chem., 43, 175 (1978).
  44. Klabunde, K.J.; Groshens, T.; Brezinski, M.; and Kennelly, W., "Hexafluoro-2-butyne-Metal Atom Chemistry.  Stable Complexes, Small Organometallic Cluster, and Metal-Acetylene Telomers," J. Amer. Chem. Soc., 100, 4437 (1978).
  45. Klabunde, K.J. Anderson, B.B.; Bader, M.; and Radonovich, L.J., "π-Arene  Complexes of Ni(II) Uniquely Stabilized by σ-Bonded Pentafluorophenyl Ligands.  Homogeneous Arene Hydrogenation Catalysis and Unusually Labile π-Arene Ligands," J. Amer. Chem. Soc., 100, 1313 (1978).
  46. Baltisberger, R.J.; Klabunde, K.J.; Stenberg, V.I.; Woolsey, N.F.; Saito, K.; and Sukalski, W., "Comparison of Solvent Refined Lignite with Solvent Refined Bituminous Coal," in Organic Chemistry of Coal, ed. L.W. Larson, ACS Symposium Series, 71, pg. 294 (1978), Fuel, 57, 529 (1978).
  47. Klabunde, K.J.; Davis, S.C.; Hattori, H.; and Tanaka, Y., "Clustering of Metal Atoms in Organic Media.  Production of Tailored Selectivity in Nickel Catalysts.  Comparisons with Raney Nickel," J. Cat., 54, 254 (1978).
  48. Klabunde, K.J.; Groshens, T.; Efner, H.F.; and Kramer, M., "An Investigation of Possible Photolysis and Thermolysis Effects in Metal Atom Cocondensation Procedures.  Crucible Insulation Effects on Metal Atom Oxidative Addition, Alkene Isomerization and Polymerization, and the Discovery of a Homogeneous Metal-Polymer Solution," J. Organomet., 157, 91 (1978).
  49. Davis, S.C. and Klabunde, K.J., "Low Temperature Cleavage of Alkanes by Small Nickel Particles.  Clustering of Metal Atoms in Organic Media VII,"  J.Amer Chem. Soc., 100, 5973 (1978).
  50. Klabunde, K.J.; Kaba, R.A.; and Morris, R., "Highly Efficient Electron Transfer Processes Over Thermally Activated Alkaline Earth Oxides. Monolayer Anion Radical Formation with Nitrobenzene-MgO and High Concentrations of CO Radicals Over MgO, CaO, SrO, BaO, and ThO2," Inorg.  Chem., 17, 2684 (1978).
  51. Klabunde, K.J., "Oxidative Addition to Metal Atoms: Mechanism, Use of Resultant Reactive RMX and R2M Species in Homogeneous Catalysis Processes  and Metal Atom-Alkane Interactions," Proceedings of 2nd International Conference on Fundamental Research in Homogeneous Catalysis, Plenum Publishers, 2, 45 (1978).
  52. Klabunde, K.J.; Ralston, D.; Zoellner, R.; Hattori, H.; and Tanaka, Y., "Solvated Metal Atoms Used for the Low temperature Preparation of Highly  Dispersed Zero Valent Metal Catalysts.  Clustering of Metal Atoms in Organic Media VI," J. Cat., 55, 213 (1978).
  53. Klabunde, K.J.; Gastinger, R.G.; Groshens, T.; and Brezinski, M., "Metal Vapor Chemistry Related to Molecular Metals," Proceedings of NATO Meeting, Les Arcs, France, Sept. 10-16 (1978), Plenum Press - invited paper, "Molecular Metals," pg. 81 (pub. 1979), W.E. Hatfield, editor.
  54. Klabunde, K.J.; Timms, P.L.; Skell, P.S.; and Ittel, S., "Introduction to  Metal Vapor Synthesis," Inorganic Syn., 19, 59 (1979), D.F. Shriver, Editor.
  55. Murdock, T.O. and Klabunde, K.J., "An Active Cadmium-Toluene Slurry and Its Use in the Preparation of Ethylcadmium Iodide," Inorg. Syn., 19, 70 (1979), D.F. Shriver, Editor.
  56. Klabunde, K.J.; Efner, H.F.; and Murdock, T.O, "Metal Atom Synthesis of Bis[1,3-(trifluoromethyl) benzene] chromium(O)," Inorg. Syn., 19, 70 (1979), D.F. Shriver, Editor.
  57. Klabunde, K.J.; Kaba, R.A.; and Morris, R.M., "Carbon Monoxide-Metal Oxide Interactions.  Surface Site Requirements for Electron Transfer Processes," ACS, Advances in Chemistry Series 173, 140 (1979), R.B. King, Editor.
  58. Klabunde, K.J.; Anderson, B.B.; and Bader, M., "Metal Atom Synthesis of η6-Toluene (Bispentafluorophenyl) nickel (II)," Inorg. Syn., 19, 72 (1979),  D.F. Shriver, Editor.
  59. Muetterties, E.L.; Schaeffer, H.; Mink, R.I.; Darensbourg, M.Y.; Miller, M.; Groshens, T.; and Klabunde, K.J., "Arene-Transition Metal Chemistry.  2. Hydrogenation of Metal-Arene and Allylmetal-Arene Complexes," Inorg. Chem., 18, 883 (1979).
  60. Klabunde, K.J., "Metal Atoms as Reactive Intermediates," major review for Plenum Press series Reactive Intermediates, ed. R. Abramovitch, Vol. 1, 37 (1979).
  61. Saito, K.; Baltisberger, R.J.; Klabunde, K.J.; Stenberg, V.I.; and Woolsey, N.F., "Evaluation of Solvents for Carbon-13 NMR Analysis of Solvent Refined Coals.  Sym-triazine, a New Carbon-13 NMR Solvent," Fuel, 58, 315 (1979).
  62. Klabunde, K.J. and Murdock, T.O., "Active Metal Slurries by Metal Vapor Techniques.  Reactions with Alkyl- and Arylhalides," J. Org. Chem., 44, 3901 (1979).
  63. Klabunde, K.J.; Gastinger, R.G.; Groshens, T.J.; and Brezinski, M., "Metal Vapor Chemistry Related to Molecular Metals," NATO Conference Series VI, Materials Science, Vol. 1, Molecular Metals, 81 (1979).
  64. Bartlett, N.; Cox, P.A.; Fischer, J.E.; Fox, W.B.; Heeger, A.J.; Klabunde, K.J.; and Shirane, G., "Metal Rich Systems," NATO Conference Series VI, Materials Science, Vol. 1, Molecular Metals, 535 (1979).
  65. Alcacer, L.; Clark, R.J.H.; Hatfield, W.E.; Klabunde, K.J.; Miller, J.S.;  Stucky, G.D.; Toombs, G.A.; Wudl, F.; and Yoshimura, "New Organometallic Systems," NATO Conference Series VI, Materials Science, Vol. 1, Molecular  Metals, 517 (1979).
  66. Klabunde, K.J., "Chemistry of Free Atoms and Particles," (238 page  monograph), Academic Press, New York, N.Y., 1980.
  67. Morris, R.M.; Kaba, R.A.; Groshens, T.G.; Klabunde, K.J.; Baltisberger, R.J.; Woolsey, N.F.; and Stenberg, V.I., "Paramagnetic Carbon Monoxide on  Magnesium Oxide," J. Amer. Chem. Soc., 102, 3419 (1980).
  68. Radonovich, L.J.; Klabunde, K.J.; Behrens, C.B.; McCollor, D.P.; and Anderson, B.B., "Crystal and Molecular Structures of π-Toluene Complexes of (C6F5)2Co and (C6F5)2Ni," Inorg. Chem., 19, 1221 (1980).
  69. Gastinger, R.G.; Anderson, B.B.; and Klabunde, K.J., "π-Arene Complexes of Nickel (II).  Synthesis (from Metal Atoms) of π-Arene (bispentafluorophenyl) nickel (II).  Properties, π-Arene Lability, and Chemistry," J. Amer. Chem. Soc., 102, 4959 (1980).
  70. Book Review, "Metal Vapor Synthesis in Organometallic Chemistry," by J.R. Blackborow and D. Young, Springer-Verlag (1979) in Synth. React. Inorg. Met.-Org. Chem., 10, 425 (1980).  Also see J. Amer. Chem Soc., 102, 6188 (1980).
  71. Patel, K.M.; Stenberg, V.I.; Baltisberger, R.J.; Woolsey, N.F.; and Klabunde, K.J., "Solubility Increase of Coal-derived Liquids by Silylation  and Acetylation: Intramolecular Hydrogen Bonding," Fuel, 59, 449 (1980).
  72. Klabunde, K.J.; Anderson, B.B.; and Neuenschwander, K., "Metal Atom Reactions with Fluorocarbons.  9. Preparation and Spectral Analyses of (Perfluoroalkyl)-and (Perfluoraryl) Palladium Halides," Inorg. Chem., 19, 3719 (1980).
  73. Sekiguchi, Y. and Klabunde, K.J., "Catalytic and Non-Catalytic Flow Pyrolysis of Bibenzyl.  Possible Homolytic and Heterolytic Processes on   Basic CaO," Fuel Proc. Tech., 4, 73 (1981).
  74. Treichel, P.M.; Essenmacher, G.P.; Efner, H.F.; and Klabunde, K.J., "An Electrochemical Study of Chromium (O) Complexes of Arenes which have Electronegative Substituent Groups," Inorganica Chimica Acta, 48, 41 (1981).
  75. Davis, S.C.; Severson, S.J.; and Klabunde, K.J., "Clustering of Metal Atoms in Organic Media.  8. Low Temperature Cleavage of Alkanes by Small Nickel Particles Resulting in Stable Nickel-Organic Composites with Unusual Magnetic and Chemical Properties," J. Amer. Chem. Soc., 103, 3024 (1981).
  76. Groshens, T.G.; Henne, B.; Bartak, D.; and Klabunde, K.J., "Metal Vapor Synthesis, Chemical Oxidation, and Electro-chemistry of Bis(Bipyridyl) Cobalt (O).  Preparation of Bromide, Tetracyanoethylene, and Tetraorganoquinodimethane Salts," Inorg. Chem., 20, 3629 (1981).
  77. Matsuo, K. and Klabunde, K.J., "Clustering of Metal Atoms in Organic Media. 9. High Activity Ni/MgO Catalysts Prepared by Metal Vapor Methods.  Surface Area and Particle Size Effects," J. Catal., 73, 216 (1982).
  78. Tanaka, Y.; Davis, S.C.; and Klabunde, K.J., "Low Temperature Reactions of Metal Atoms with Methyl Bromide," J. Amer. Chem. Soc., 104, 1013 (1982).
  79. Davis, S.C. and Klabunde, K.J., "Unsupported Small Metal Particles: Preparation, Reactivity, and Characterization," Chem. Rev., 82, 153 (1982).
  80. Radonovich, L.J.; Erying, M.W.; Groshens, T.G.; and Klabunde, K.J., "Synthesis, Chemistry, and Structure of a New π-Arene Complex of Iron (O).  (η6-Toluene)(2,2'-bipyridine) Fe(O).  Structural Evidence for Extensive Back π-Bonding to 2,2'-Bipyridine," J. Amer. Chem. Soc., 104, 2816 (1982).
  81. Matsuo, K. and Klabunde, K.J.; "Clustering of Metal Atoms in Organic Media. II. The Effect of Support on Nickel Catalysts Prepared by Solvated Metal Atom Dispersion (SMAD)," J. Org. Chem., 47, 843 (1982).
  82. Groshens, T.G. and Klabunde, K.J., "Preparation of (η6-Toluene)bis (trichlorosilyl)nickel(II) by Oxidative Addition of Silicon-Silicon and Silicon-Hydrogen Bonds to Ni Atoms and Bis(1,5-cyclooctadiene)Nickel(O).  Extreme Lability of the π-Toluene Ligand," Organometallics, 1, 564 (1982).
  83. Ralston, D. and Klabunde, K.J., "Clustering of Metal Atoms in Organic Media. 10. Various Arene Nickel Atom Systems Employed for the Preparation of Ni-Powder and Ni-Al2O3 Catalysts.  Surface Area, Catalytic, and X-Ray Photoelectron Spectroscopy Studies," Applied Catalysis, 3, 13 (1982).
  84. Brezinski, M. and Klabunde, K.J., "Complexes of (C6F5)2Co and Ni.  Synthesis of (π-Arene)bis(pentafluorophenyl)cobalt(II) Using Cobalt Atoms.  Reactions, π-Arene Lability, and Use in Synthesis of Tetrahedral (C6F5)2Co(L)2," Organometallics, 2, 1116 (1983).
  85. Morris, R.M. and Klabunde, K.J., "The Formation of Paramagnetic Adsorbed Molecules on Thermally Activated Magnesium and Calcium Oxides. Characteristics of the Active Surface Sites," Inorg. Chem., 22, 682 (1983).
  86. Morris, R.M. and Klabunde, K.J., "The Formation of Paramagnetic Adsorbed  Molecules on Thermally Activated Magnesium and Calcium Oxides.  Further Studies of Carbon Monoxide," J. Amer. Chem. Soc., 105, 2633 (1983).
  87. Klabunde, K.J. and Tanaka, Y., "Activation of Methane with Atoms at 10°K  Without Photolysis," J. Amer. Chem. Soc., 105, 3544 (1983).
  88. Klabunde, K.J. and Tanaka, Y., "The Building of a Catalytic Metal Particle  One Atom at a Time.  Solvated Metal Atom Dispersed Catalysts," J. Molecular Catal., 21, 57-79 (1983).
  89. Klabunde, K.J.; Tanaka, Y.; and Imizu, Y., "New Catalytic Materials Produced by Metal Vapor Techniques," Chem. Eng. News, Sept. 12, 45 (1983).
  90. Groshens, T.J. and Klabunde, K.J., "Carbonyl Compounds of Cobalt (II) and Nickel (II).  Reversible Arene-Carbon Monoxide Exchange and Similarities to η6-Arene Complexes," J. Organomet. Chem., 259, 337-343 (1983).
  91. Klabunde, K.J. and Imizu, Y., "Bimetallic Solvated Metal Atom Dispersed Catalysts.  New Materials with Low Temperature Catalytic Properties," J.  Amer. Chem. Soc., 106, 2721 (1984).
  92. Klabunde, K.J.; Kramer, M.P.; Senning, A.; and Moltzen, E.K., "Carbon Monosulfide Chemistry in Solution.  Insertion into Sulfur-Chlorine Bonds,"  J. Amer. Chem. Soc., 106, 263 (1984).
  93. Lin, S.T.; Groshens, T.J.; and Klabunde, K.J., "Conversion of (π-Allyl)- Nickel Complexes to (π-Arene)Nickel Complexes," Inorg. Chem., 23, 1 (1984).
  94. Moltzen, E.K.; Senning, A.; Kramer, M.P.; and Klabunde, K.J., "Carbon Monosulfide Chemistry in Solution.  II. Synthesis and Reactions of Trichloromethyl Chlorothioformate," J. Org. Chem., 49, 3854 (1984).
  95. Imizu, Y. and Klabunde, K.J., "Metal Cluster vs. Atom Reactivities: Magnesium Cluster Grignard Reagents," Inorg. Chem., 23, 3602 (1984).
  96. Klabunde, K.J. and Imizu, Y., "Unusual Bimetallic Catalyst Synthesized.  A Manganese-Cobalt Catalyst Prepared by Solvated Metal Atom Dispersion Has  Some Unusual Catalytic Properties," Science, 224, 1329 (1984) (written by Thomas Maugh II).
  97. Krebs, A.; Guntner, A.; Senning, A.; Moltzen, E.K.; Klabunde, K.J.; and Kramer, M.P., "[1+2]-Cycloadditions of Carbon Monosulfide with Aminoalkynes," Angew. Chemie, Int. Ed., 23, 729 (1984).
  98. Zoellner, R.W. and Klabunde, K.J., "The Reactions of Metal Atoms with Alkynes.  2. Co-condensation Reactions of Germanium and Tin Atoms with Acetylene, and the Formation of Integral Metal-Acetylene Polymers," Inorg. Chem., 23, 3241 (1984).
  99. Zoellner, R.W. and Klabunde, K.J., "Metal Atom Reactions with Alkynes," Chem. Rev., 84, 545-559 (1984).
  100. Lin, S.T.; Narske, R.N.; and Klabunde, K.J., "Synthesis of (η6-arene)NiR2 and CoR2(R=σ-bound Halosilanes and Haloarenes) by (allyl)2Ni/HR Reactions and Combined Metal Trifluoroacetate Grignard Reagent Methods," Organometallics, 3, 571-574 (1985).
  101. Imizu, Y. and Klabunde, K.J., "Solvated Metal Atom Dispersed (SMAD) Catalysts.  Highly Active Bimetallic Systems," " Catalysis of Organic Reactions," R.L. Augustine, editor, Marcel Dekker, (1985), pp. 225-250.
  102. Lin, S.T. and Klabunde, K.J., "Oxidative Addition to Platinum Atoms," Inorg. Chem., 24, 1961-1963 (1985).
  103. Radonovich, L.J.; Janikowski, S.; Groshens, T.J.; and Klabunde, K.J., "Bistrichlorosilyl tricarbonylnickel (II).  Synthesis and Structure," Organometallics, 3, 396-398 (1985).
  104. Brezinski, M.; Klabunde, K.J.; Janikowski, S.K.; and Radonovich, L.J., "The Novel Displacement of a η6-Arene by η5-Cyclopentadienide.  Synthesis and Structure of [(η5-C5H5)Ni(C6F5)2][(C2H5)4N]," Inorg. Chem., 24, 3305-3307 (1985).
  105. Ammeter, J.H.; Elschenbroich, C.; Groshens, T.J.; Klabunde, K.J.; Kuhne, R.O.; and Mockel, R., "Metal-π-Complexes of Benzene Derivatives.  22. The Ground-State Configuration of (η6-Toluene)bis(η1-pentafluorophenyl)cobalt (II): An EPR Study," Inorg. Chem., 24, 3307-3310 (1985).
  106. Lin, S.T. and Klabunde, K.J., "Thermally Activated Magnesium Oxide Surface Chemistry.  Adsorption and Decomposition of Phosphorus Compounds," Langmuir, 1, 600-605 (1985).
  107. Klabunde, K.J. (editor), Thin Films from Free atoms and Particles, Academic Press, Orlando (1985).
  108. Klabunde, K.J., "Introduction to Free Atoms and Particles," in Thin Films  from Free atoms and Particles, K.J. Klabunde, editor, Academic Press, Orlando (1985), pg. 1-21.
  109. Nieman, G. and Klabunde, K.J., "Clustering of Free Atoms and Particles.   Polymerization and the Beginning of Film Growth," in Thin Films from Free Atoms and Particles, K.J. Klabunde, editor, Academic Press, Orlando (1985).
  110. Kanai, H.; Choe, S.B.; and Klabunde, K.J., "Isomerization of 1-Butene by  (η6-Arene)NiR2.  A Very Active Homogeneous Catalyst System," J. Amer. Chem.  Soc., 108, 2019-2023 (1986).
  111. Hoq, M.F. and Klabunde, K.J., "Thermally Activated Magnesium Oxide as a   Selective Dueteration Catalyst Under Mild Conditions," J. Amer. Chem. Soc., 108, 2114-2116 (1986).
  112. Klabunde, K.J. and Imizu, Y., U.S. Patent 4,588,708, May (1986), "Bimetallic Solvated Metal Atom Dispersed Catalysts."
  113. Klabunde, K.J. and  Whetten, A., "Metal Cluster vs. Atom Reactivities.  Calcium and Magnesium Vapor with Alkyl Halides and Methane," J. Amer. Chem. Soc., 108, 6529-6534 (1986).
  114. Meier, P.F.; Pennella, F.; Imizu, Y.; and Klabunde, K.J., "Iron and Cobalt Fischer-Tropsch Catalysts Prepared by the Solvated Metal Atom Technique,"  J. Catal., 101, 545-54 (1986).
  115. Klabunde, K.J., book review of "Stereochemistry of Heterogeneous Metal Catalysis," M. Bartok and coworkers, J. Amer. Chem. Soc., 108, 5049 (1986).
  116. Brezinski, M.; Klabunde, K.J.; and Anderson, B.B., "(η6-Toluene)bis (pentafluorophenyl)cobalt(II)," Organometallic Syntheses, 3, 158-160 (1986).
  117. Lin, S.T. and Klabunde, K.J., "(η6-Toluene)bis(pent-chlorophenyl) nickel(II)," Organometallic Syntheses, 3, 150-152 (1986).
  118. Choe, S.B. and Klabunde, K.J., "(η6-Toluene)bis(trichlorosilyl)nickel(II)," Organometallic Syntheses, 3, 153-155 (1986).
  119. Choe, S.B. and Klabunde, K.J., "(η6-Toluene)bis(trifluorosilyl)nickel(II)," Organometallic Syntheses, 3, 156-157 (1986).
  120. Lin, S.T. and Klabunde, K.J., "(η6-Toluene)bis(pentafluorophenyl) nickel(II)," Organometallic Syntheses, 3, 147-149 (1986).
  121. Jeong, G.H. and Klabunde, K.J., "Metal Atom Reactions with Methane.  Boron, Aluminum, Gallium, Indium Atoms and Dimers," J. Amer. Chem. Soc., 108, 7103 (1986).
  122. Lin, S.T.; Franklin, M.T.; and Klabunde, K.J., "Non-Aqueous Colloidal Gold. Clustering of Metal Atoms in Organic Media. 12.," Langmuir, 2, 259-260 (1986).
  123. Kanai, H.; Tan, B.J.; and  Klabunde, K.J., "Fischer-Tropsch Reactions Over Mono- and Bimetallic SMAD Catalysts," Langmuir, 2, 760-765 (1986).
  124. Franklin, M.T. and Klabunde, K.J., "Living Colloidal Metal Particles from Solvated Metal Atoms.  Clustering of Metal Atoms in Organic Media 15.," ACS Chemistry Series, High Energy Methods in Organometallic Chemistry, Suslick, K., editor, ACS Symposium Series 333, p. 246-259 (1987).
  125. Klabunde, K.J. and Matsuhashi, H., "A Comparison of Electron Donor and Proton Abstraction Activities of Thermally Activated Pure Magnesium Oxide and Doped Magnesium Oxides," J. Amer. Chem. Soc., 109, 1111-1114 (1987).
  126. Klabunde, K.J.; Hoq, M.F.; Mousa, F.; and Matsuhashi, H., "Metal Oxides and Their Physico-Chemical Properties in Catalysis and Synthesis," invited book chapter in Preparative Chemistry Using Supported Reagents, Laszlo, P., editor, Academic Press, pg. 35-57 (1987).
  127. Olsen, A. and Klabunde, K.J., "Metal Particles and Metal Cluster Compounds," Encyclopedia of Physical Science and Technology, 8, 111-146 (1987).
  128. Moltzen, E.K.; Kramer, M.P.; Senning, A.; and Klabunde, K.J., "Studies on the Reactivity of Carbonmonosulfide Toward Amines and Thiols," J. Org. Chem., 52, 1156-1161 (1987).
  129. Li, Yong-Xi and Klabunde, K.J., "Pt-Sn/Al2O3 Bimetallic Catalysts Prepared by Solvated Metal Atom Dispersion (SMAD).  Synthesis and Catalytic Performance," Langmuir, 3, 558-562 (1987).
  130. Groshens, T.J. and Klabunde, K.J., "Heated Inlet System for Cocondensation Metal Atom Reactor," invited contribution for New Developments in the  Synthesis, Manipulation, and Characterization of Organometallic Compounds, ACS Symposium Series 357, Wayda, A.L. and Darensbourg, M.Y., editors, American Chem. Soc., pg. 190-193 (1987).
  131. Groshens, T.J. and Klabunde, K.J.; "Recovering Air Sensitive Products from Metal Atom Reactors," invited contribution for New Developments in the Synthesis, Manipulation, and Characterization of Organometallic Compounds, ACS Symposium Series 357, Wada, A.L. and Darensbourg, M.Y., editors, American Chem. Soc., pg. 193-194 (1987).
  132. Cardenas-Trivino, G.; Klabunde, K.J.; and Dale, B., "Living Colloidal Palladium in Non-Aqueous Solvents, Formation, Stability, and Film Forming  Properties.  Clustering of Metal Atoms in Organic Media 14," Langmuir, 3, 986-992 (1987).
  133. Klabunde, K.J., book review of "Highly Dispersed Metals," W.Romanowski,   Organometallics, 6, 2460 (1987).
  134. Cardenas-Trivino, G.; Klabunde, K.J., and Dale, B., "Thin Metallic Films from Solvated Metal Atoms," SPIE Proceedings (Optical Engineering), paper  821-19 (8 pages), pg. 206-213 (1987).
  135. Cardenas-Trivino, G.; Shevlin, P.B.; and Klabunde, K.J., "Reactions of Iron(II) Oxide with Alkenes at 77°K," Inorganica Chimica Acta., 131, 1-2 (1987).
  136. Klabunde, K.J. and Nieves, I., "Interaction of Activated Magnesium Oxide  Surfaces with Spin Traps," J. Phys. Chem., 92, 2521-2525 (1988).
  137. Nieves, I. and Klabunde, K.J., "Nature of Chemisorbed Species on Metal Oxide Surfaces.  Electron Transfer and Bond Breaking Processes," invited book chapter for Advances in Basic Solid Materials.  Materials Chemistry and Physics, Tanabe, K.,  editor, Elsevier, 18, 485-498 (1988).
  138. Li, Yong-Xi and Klabunde, K.J., "Spectroscopic Characterization of Pt-Sn Bimetallic Catalysts Prepared by Solvated Metal Atom Dispersion (SMAD),"  Langmuir, 4, 385-391 (1988).
  139. Moltzen, E.K.; Klabunde, K.J.; and Senning, A., "Carbon Monosulfide - A Review," Chem. Rev., 88, 391-406 (1988).
  140. Akhmedov, V. and Klabunde, K.J., "Highly Activated Re-Pt/MO Catalysts for  C-C Bond Cleavage Reactions.  Preparation by Solvated Metal Atom Dispersion (SMAD)," J. Molec. Catal., 45, 193-206 (1988).
  141. Klabunde, K.J.; Li, Yong-Xi; and Purcell, K.F., "Mossbauer and XPS Studies of Pt-Sn Catalysts Prepared by Solvated Metal Atom Dispersion (SMAD)," Hyperfine Interactions, 41, 649-652 (1988).
  142. Li, Yong-Xi and Klabunde, K.J., "A Study of Pt-Fe/Al2O3 Catalysts Prepared by Solvated Metal Atom Dispersion (SMAD)," Hyperfine Interactions, 41, 665-668 (1988).
  143. Klabunde, K.J., "Catalyst Coating Puts Thin Films on Irregular Surfaces," Advanced Coating and Surface Technology, 2, (1988).
  144. Li, Yong-Xi and Klabunde, K.J., "Bimetallic Pt-Fe.Al2O3 Catalyst Prepared by Solvated Metal Atom Dispersion (SMAD)," New Journal of Chem., (France), 12, 691-696 (1988).
  145. Tan, B.J.; Klabunde, K.J.; Tanaka, T.; Kanai, H.; and Yoshida, S., "An EXAFS Study of Co-Mn/SiO2 Bimetallic Solvated Metal Atom Dispersed (SMAD) Catalysts," J. Amer. Chem. Soc., 110, 5951-5958 (1988).
  146. Ekerdt, J.G.; Klabunde, K.J.; Shapley, J.R.; White, J.M.; and Yates, J.T.,  "The Surface Chemistry of Organo-phosphorus Compounds," J. Phys. Chem., 92, 6182-6188 (1988).
  147. Cardenas-Trivino, G. and Klabunde, K.J., "Characterization of Metallic Thin Films Prepared by Chemical Liquid Deposition (CLD): Colloidal Metal Particles in Non-Aqueous Solvents," Bulletin, Chemical Society of Chile, 33(4), 163-175 (1988).
  148. Nafis, S.; Tang, Z.X.; Dale, B.; Sorensen, C.M.; Hadjipanayis, G.C.; and Klabunde, K.J., "Magnetic Studies of Fine Iron and Iron-Oxide Particles,"  J. Appl. Phys., 64, 5835-5837 (1988).
  149. Choe, S.B. and Klabunde, K.J., "New η6-Arene Complexes of Ni(II): Polyarene and Fused Arene Systems," J. Organometallic Chem., 359, 409-418 (1989).
  150. Utamapanya, S.; Ortiz, J.V.; and Klabunde, K.J., "Theoretical Calculations  on the Interaction of CO with MgO and CaO," J. Amer. Chem. Soc., 111, 799-802 (1989).
  151. Klabunde, K.J. and Campostrini, R., "Perfluoro-n-octylpalladium and Zinc  Bromides.  Remarkably Stable Coordinatively Unsaturated Organometallics," J. Fluorine Chem., 42, 93-104 (1989).
  152. Starowieyski, K.B. and Klabunde, K.J., "Organogallium Compounds From Metallic Gallium Through the Use of Metal Vapor Synthesis," J. Applied Organomet. Chem., 3, 219-224 (1989).
  153. Choe, S.B.; Kanai, H.; and Klabunde, K.J., "Catalytic Dimerization of Ethylene and Propylene by (η6-Arene)NiR2 and in Combination with Alkylaluminum Halides.  Production of Highly Active Homogeneous Catalysts," J. Amer. Chem. Soc., 111, 2875-2882 (1989).
  154. Hoq, M.F. and Klabunde, K.J., "Activation Energies for Carbon Acid/D2  Exchange Over a Solid Base Catalyst.  Correlation with Gas Phase Acidities," Proceedings of Int. Conf. Acid-Base Catalysis, Hokkaido Japan, December 1988, in "Acid-Base Catalysis," editors, Tanabe, K.; Hattori, H.; Yamaguchi, T.; and Tanaka, T., published by Kadansha, Ltd., Tokyo, Japan, 105-121 (1989).
  155. Zuckerman, E.B.; Klabunde, K.J.; Oliver, B.J.; and Sorensen, C.M., "Non- Aqueous Perfluorocarbon-Derived Gold Colloids.  Clustering of Metal Atoms in Fluorocarbon Media. 1," Chem. of Materials, 1, 12-14 (1989).
  156. Jeong, G.H. and Klabunde, K.J., "Matrix Induced Frequency Shifts of Transition Metal Atoms in Ar, Kr, and Xe Matrices at 10°K," J. Chem. Phys., 91, 1958-1970 (1989).
  157. Klabunde, K.J.; Habdas, J.; Cardenas-Trivino, G., "Colloidal Metal Particles Dispersed in Monomeric and Polymeric Styrene and Methylmethacrylate," Chem. of Materials, 1, 481-483 (1989).
  158. Brezinski, M.; Schneider, J.; Radonovich, L.; and Klabunde, K.J., "η6-Arene Displacement by Halide Ions.  Synthesis and Structural Characterization of Chloro- and Fluoro-Bridged Organonickel Complexes (R=C6H5, SiCl3)," Inorg. Chem., 28, 2414-2419 (1989).
  159. Klabunde, K.J.; Moltzen, E.; and Voska, K., "Carbon Monosulfide Chemistry. Reactivity and Polymerization Studies," XIII Int. Sym. Org. Chem. Sulfur, August 1988, Odense, Denmark.  Full paper in the proceedings of this meeting; Phosphorus, Sulfur, and Silica, 43, 47-61 (1989).
  160. Jeong, G.H.; Klabunde, K.J.; Pan, O.G.; Paul, G.C.; and Shevlin, P.B., "Reactions of Carbon Atoms/Clusters with Methane, Methylbromide, and Water at 10°K and 77°K," J. Amer. Chem. Soc., 111, 8784-8790 (1989).
  161. Tang, Z.X.; Nafis, S.; Sorensen, C.M.; Hadjipanayis, G.C.; and Klabunde, K.J., "Magnetic Properties of Aerosol Synthesized Iron Oxide Particles," J. of Magnetism and Magnetic Materials, 80, 285-289 (1989).
  162. Choe, S.B.; Schneider, J.J.; Klabunde, K.J.; Radonovich, L.J.; and Ballintine, T.A., "New Silyl-Nickel Complexes Prepared by η6-Arene Substitution in (η6-Toluene)(trihalosilyl)nickel.  Preparation of L3Ni(SiX3)2 and L2Ni(SiX3)2 (X=Cl,F; L=phosphine, phosphites, and pyridines).  X-Ray Structure of (cis)-Collidine2Ni(SiCl3)2," J. Organomet. Chem., 376, 419-439 (1989).
  163. Nafis, S.; Hadjipanayis, G.C.;Sorensen, C.M.; and Klabunde, K.J., "Magnetic Properties of Fine Fe-B Particles,: IEEE Trans. Mag., 25, 3641-3643 (1989).
  164. Tang, Z.X.; Nafis, S.; Sorensen, C.M.; Hadjipanayis, G.C.; and Klabunde, K.J., "Magnetic and Structural Properties of Aerosol Synthesized Barium   Ferrite Particles," IEEE Trans. Mag., 25, 4236-4238 (1989).
  165. Yiping, L.; Hadjipanayis, G.C.; Sorensen, C.M.; and Klabunde, K.J., "Magnetic and Structural Properties of Ultrafine Co-B Particles," J. of Magnetism and Magnetic Materials, 79, 321-326 (1989).
  166. Klabunde, K.J., "Method of Coating Substrates with Solvated Clusters of Metal Particles," U.S. Patent No. 4,877,647, October (1989).
  167. Tan, B.J.; Sherwood, P.M.A.; and Klabunde, K.J., "XPS Studies of Gold Films Prepared from Non-Aqueous Gold Colloids," Langmuir, 6, 105-113 (1990).
  168. Kernizan, C.F.; Klabunde, K.J.; Sorensen, C.M.; and Hadjipanayis, G.C., "Magnetic
  169. Behavior of Nano-scale Iron Particles Generated by Iron Atom    Clustering in Cold Pentane," Chem. of Materials, 2, 70-74 (1990).
  170. Klabunde, K.J., invited book review of "Electrons in Metals and Alloys," by Alonso, J.A. and March, N.H., J. Amer. Chem. Soc., 112, 1664 (1990).
  171. Tan, B.J.; Klabunde, K.J.; and Sherwood, P.M.A., "X-Ray Photoelectron Spectroscopy Studies of Solvated Metal Atom Dispersed Catalysts. Monometallic Iron and Bimetallic Iron-Cobalt Particles on Alumina," Chem.  of Materials, 2, 186-191 (1990).
  172. Klabunde, K.J.; Jeong, G.H.; and Olsen, A.W., "Ground State Metal Atoms and Clusters in Low Temperature C-H and C-C Activation.  Periodic Trends and Unusual Structural Effects," invited paper for Carbon-Hydrogen Activation volume in book series Molecular Structure and Energetics, Selective Hydrocarbon Activation, Davies, J.A.; Watson, P.L.; Greenburg, A.; Liebman, J.F., editors, VCH Publishers, New York, NY, pgs. 433-463 (1990).
  173. Nafis, S.; Hadjipanayis, G.C.; Sorensen, C.M.; and Klabunde, K.J., "Magnetic Properties of Ultrafine Fe-Ni-B Particles," J. Appl. Phys., 67, 4478-4480 (1990).
  174. Yiping, L.; Hadjipanayis, G.C.; Sorensen, C.M.; and Klabunde, K.J.,, "Magnetic Properties of Fine Cobalt Particles Prepared by Metal Atom Reduction," J. Appl. Phys., 67, 4502-4504 (1990).
  175. Kernizan, C.F.; Klabunde, K.J.; Hadjipanayis, G.C.; and Sorensen, C.M.,   "Magnetic Properties of Nano-scale Iron Particles," J. Appl. Phys., 67, 5897-5898 (1990).
  176. Groshens, T.J. and Klabunde, K.J., "Molecular Vapor Synthesis: The Use of  Titanium Monoxide and Vanadium Monoxide Vapors as Reagents," Inorg. Chem., 29, 2979-2982 (1990).
  177. Hoq, M.F.; Nieves, I.; and Klabunde, K.J., "Mechanistic Studies of Hydrogen CH/D2 Exchange Over Thermally Activated Magnesium Oxide," J. Catal., 123, 349-363 (1990).
  178. Li, Y.X. and Klabunde, K.J., "Studies of Pt-Sn/Al2O3 Catalysts Prepared by Pt and Sn Co-evaporation (Solvated Metal Atom Dispersion)," J. Catal., 126, 173-186 (1990).
  179. Jeong, G.H.; Boucher, R.; and Klabunde, K.J., "Reactions of Boron Atoms and Clusters with Methane, Methylbromide, and Water Under Matrix Isolation Conditions," J. Amer. Chem. Soc., 122, 3332-3337 (1990).
  180. Cardenas-Trivino, G.; Camilo-Retamal, C.; and Klabunde, K.J., "Thermal Stability and Molecular Weights of Polystyrene Metal Polymers," Bol. Soc.  Quim., Chile, 35, 223-228 (1990).
  181. Cardenas-Trivino, G.; Alvial, M.J.; and Klabunde, K.J., Germanium Colloids in Non-Aqueous Solvents and Thin Films Prepared by Chemical Liquid Deposition. II.," Bol. Soc. Quim., Chile, 35, 277-285 (1990).
  182. Papaefthymiou, V.; Kostikas, A.; Simopoulos, A.; Niarchos, D.; Gangopadyay, S.; Hadjipanayis, G.C.; Sorensen, C.M.; and Klabunde, K.J., "Magnetic hysteresis and Mossbauer studies in ultrafine iron Particles", J. Appl. Phys., 67 (9), 4487-4489 (1990).
  183. Tan, B.J.; Klabunde, K.J.; and Sherwood, P.M.A., "X-Ray Photoelectron Spectroscopy Studies of Solvated Metal Atom Dispersed (SMAD) Catalysts.   Evidence for Layered Cobalt-Manganese Particles on Alumina and Silica," J.  Amer. Chem. Soc., 113, 855-861 (1991).
  184. Utamapanya, S.; Klabunde, K.J.; and Schulp, J.R., "Nano-scale Metal Oxide Particles/Clusters as Chemical Reagents.  Synthesis and Properties of Ultra-High Surface Area Magnesium Hydroxide and Magnesium Oxide," Chem. Materials, 3, 175-181 (1991).
  185. Atteya, M. and Klabunde, K.J., "Nano-scale Metal Oxide Particles as Chemical Reagents.  Heats of Adsorption of Heteroatom Containing Organics on Heat Treated Magnesium Oxide Samples of Varying Surface Area," Chem. Materials, 3, 182-187 (1991).
  186. Klabunde, K.J.; Li, Y.X.; and Tan, B.J., "Solvated Metal Atom Dispersed Catalysts" (invited review article), Chem. Materials, 3, 30-39 (1991).
  187. Li, Y.X.; Klabunde, K.J.; and Davis, B.H., "Alloy Formation in Supported Pt-Sn Catalysts.  Mossbauer Studies," J. Catal., 128, 1-12 (1991).
  188. Li, Y.X. and Klabunde, K.J., "Nano-scale Metal Oxide Particles as Chemical Reagents.  Destructive Adsorption of a Chemical Agent Simulant, Dimethylmethylphosphonate (DMMP) on Heat Treated Magnesium Oxide," Langmuir, 7, 1388-1393 (1991).
  189. Li, Y.X.; Schulp, J.R.; and Klabunde, K.J., "A Fourier Transform Infrared  Photoacoustic Spectroscopy (FT-IR-PAS) Study of the Adsorption of Organophosphorous Compounds on Heat Treated Magnesium Oxide," Langmuir, 7, 1394-1399 (1991).
  190. Klabunde, K.J., "Formation of Carbon-Transition and Inner Metal Bond from  Monoolefins.  η2-η-Olefin Complexes by Reaction of Metal Vapors with Monoolefins," Zuckerman, J.J.; Hagan, A.P, editors, Inorganic Reactions and Methods, Vol. 12a, pg. 53-55 (1991).
  191. Klabunde, K.J., "Formation of Carbon-Transition and Inner Transition Metal Bond.  Chelating Dienes by Metal Atom and Related Reactions," Zuckerman,  J.J.; Hagan, A.P., editors, Inorganic Reactions and Methods, Vol. 12a, pg. 181-183 (1991).
  192. Klabunde, K.J., "Formation of Carbon-Transition and Inner Transition Metal Bond from Arenes by Metal Atom and Related Methods," Zuckerman, J.J.; Hagan, A.P., editors, Inorganic Reactions and Methods, Vol.12a, pg. 225-232 (1991).
  193. Klabunde, K.J., "Formation of Carbon-Transition and Inner Transition Metal Bond from Alkynes by Metal Atom and Related Methods," Zuckerman, J.J.; Hagan, A.P., editors, Inorganic Reactions and Methods, Vol.12a, pg. 264-267 (1991).
  194. Klabunde, K.J., "Formation of Carbon-Transition and Inner Transition Metal Bond from Conjugated Dienes.  π-Allyl Complexes by Metal Atom Reactions," Zuckerman, J.J.; Hagan, A.P., editors, Inorganic Reactions and Methods, Vol.12a, pg. 167-169 (1991).
  195. Yiping, L.; Hadjipanayis, G.C.; Sorensen, C.M.; and Klabunde, K.J., "Magnetic Properties of Fine Fe-Co-B Particles Prepared by Chemical Reduction," J. Appl. Phys., 69, 5141-5143 (1991).
  196. Tang, Z.X.; Sorensen, C.M.; Klabunde, K.J.; and Hadjipanayis, G.C., "Size-  Dependent Magnetic Properties of Manganese Ferrite Fine Particles," J. Appl. Phys., 69, 5279-5281 (1991).
  197. Cardenas-Trivino, G.; Retamal, C.; and Klabunde, K.J., "Synthesis and Molecular Weights of Metal Poly(methylmethacrylates)," Polymer Bulletin, 25, 315-318 (1991).
  198. Klabunde, K.J.; Tan, B.J.; and Sherwood, P.M.A., "Cobalt-Manganese Bimetallic Catalysts Prepared from Solvated Metal Atoms: Layered Structures Examined by X-ray Photoelectron Spectroscopy," in Catalytic Science and Technology, Vol. 1, Yoshida, S.; Takezawa, N.; and Ono, T., editors, Kodansha Publications, Tokyo and VCH Publications, New York, NY, pg. 141-145 (1991).
  199. Klabunde, K.J. and Li, Y.X., "Platinum-Tin Bimetallic Catalysts Prepared from Solvated Metal Atoms," in Catalytic Science and Technology, Vol. 1, Yoshida, S.; Takezawa, N.; and Ono, T., editors, Kodansha Publications, Tokyo and VCH Publications, New York, NY, pg. 525-526 (1991).
  200. Hooker, P.; Tan, B.J.; Klabunde, K.J.; and  Suib, S., "The Preparation of Nickel Carbide Ultra Fine Particles by Metal Vapor Methods," Chem. Materials, 3, 947-952 (1991).
  201. Glavee, G.N.; Kernizan, C.F.; Klabunde, K.J.; Sorensen, C.M.; and Hadjipanayis, G.C., "Clusters of Immiscible Metals.  Iron-Lithium Nano-scale Bimetallic Particle Synthesis and Behavior Under Thermal and Oxidative Treatments," Chem. Materials, 3, 967-976 (1991).
  202. Tang, Z.X.; Sorensen, C.M.; Klabunde, K.J.; and Hadjipanayis, G.C., "Preparation of Manganese Ferrite Fine Particles from Aqueous Solution," J. Colloid Interface Science, 146, 38-52 (1991).
  203. Cardenas-Trivino, G.; Retamal, C.C.; and Klabunde, K.J., "Polystyrene Metal Polymers", J. Appl. Polymer Sci.:  Applied Polymer Sym., 49, 15-28 (1991).
  204. Tang, Z.X.; Sorensen, C.M.; Klabunde, K.J.; and Hadjipanayis, G.C., Size-Dependent Curie Temperature in Nanoscale MnFe2O4 Particles, Phys. Rev. Letters, 67, 3602-3605 (1991).
  205. Boucher, R.; Wang, Y.; and Klabunde, K.J., "Laser Evaporation of Boron for Study of Boron Atom Reactions with Oxygen.  Characterization of Boron Dioxide and an Oxygen Adduct in Frozen Inert Matrices", High Temp Sci., 31, 87 (1991).
  206. Tang, Z.X.; Chen, J.P.; Sorensen, C.M.; Klabunde, K.J.; and Hadjipanayis, C.G., Reply to "Comment on Size-Dependent Curie Temperature in Nanoscale MnFe2O4 Particles", Phys. Rev. Letters, 68, 3114 (1992).
  207. Klabunde, K.J., "Solvated Atoms of Platinum, Palladium and Gold, Precursors to Colloids, Films and Catalysts", Platinum Metals Rev., 36, (2), 80-84, (1992).
  208. Li, Y.-X. and Klabunde, K.J., "Heterophasic Isotope Exchange in Nanoscale Metal Oxide Particles.  Lattice Oxygen and Surface OH Groups with Water Vapor (D2O and H218O), Chem. Mater., 4, 611-615 (1992).
  209. Zhang, X. and Klabunde, K.J., "Superoxide (O2-) on the Surface of Heat-Treated Ceria.  Intermediates in the Reversible Oxygen to Oxide Transformation", Inorganic Chemistry, 31, 1706-1709 (1992).
  210. Yiping, L.; Hadjipanayis, G.C.; Sorensen, C.M.; and Klabunde, K.J., "Size Effects on the Magnetic Properties of Fe-Co-B Powders", J. Magn. Magn. Mater., 104-107, 1545-1546 (1992).
  211. Gangopadhyay, S.; Hadjipanayis, G.C.; Dale, B.; Sorensen, C.M.; Klabunde, K.J.; Papaefthymiou, V.; Kostikas, A., "Magnetic Properties of Ultrafine Iron Particles", Physical Review B, 45, 9778-9787 (1992).
  212. Xu, H.K.; Sorensen, C.M.; Klabunde, K.J.; and Hadjipanayis, G.C., "Aerosol Synthesis of Gadolinium Iron Garnet Particles", J. Mater. Res., 7, 712-716 (1992).
  213. Glavee, G.N.; Jagirdar, B.R.; Schneider, J.J.; Klabunde, K.J.; Radonovich, L.J.; and Dodd, K., "Synthesis, Chemistry, and Structures of Mono-η6-arene Complexes of Chromium(II) Bearing Trichlorosilyl and Carbon Monoxide Ligands", Organometallics, 11, 1043-1050 (1992).
  214. Li, Y.-X.; Koper, O.; Atteya, M.; and Klabunde, K.J., "Adsorption and Decomposition of Organophosphorus Compounds on Nanoscale Metal Oxide Particles.  In Situ GC-MS Studies of Pulsed Microreactions over Magnesium Oxide", Chem. Mater., 4, 323-330 (1992).
  215. Glavee, G.N.; Klabunde, K.J.; Sorensen, C.M.; and Hadjipanayis, G.C., "Borohydride Reductions of Metal Ions.  A New Understanding of the Chemistry Leading to Nanoscale Particles of Metals, Borides, and Metal Borates", Langmuir, 8, 771-773 (1992).
  216. Hadjipanayis, G.C.; Tang, Z.X.; Gangopadhyay, S.; Yiping, L.; Sorensen, C.M.; Klabunde, K.J.; Kostikas, A.; and Papaefthymiou, V., "Preparation of Fine Particles/Magnetic Properties of Fine Particles", in "Studies of Magnetic Properties of Fine Particles and Their Relevance to Materials Science", Dormann, J.L. and Fiorani, D., editors, Elsevier Publishers, B.V., 35-46 (1992).
  217. Glavee, G.N.; Easom, K.; Klabunde, K.J.; Sorensen, C.M.; and Hadjipanayis, G.C., "Clusters of Immiscible Metals.  2.  Magnetic Properties of Iron-Lithium Bimetallic Particles", Chem. Mater., 4, 1360-1363 (1992).
  218. Lee, K.M., Sorensen, C.M.; Klabunde, K.J.; and Hadjipanayis, G.C., "Synthesis and Characterization of Stable Colloidal Fe3O4 Particles in Water-In-Oil Microemulsions", IEEE Transactions on Magnetics, Vol. 28, No. 5, 3180-3182 (1992).
  219. Klabunde, K.J.; Youngers, G.; Zuckerman, E.B.; Tan, B.J.; Antrim, S.; and Sherwood, P.M., "Living Colloidal Metal Particles in Non-aqueous Solvents as Precursors for Thin Films by Chemical Liquid Deposition (CLD).  Gold Coatings on Glass, Metals, Silicon, and Organic Polymers Employing Organic and Fluororganic Solvents", Eur. J. Solid State Inorg. Chem., 29, 227-260 (1992).
  220. Wang, Y.; Li, Y-X.; and Klabunde, K.J., "Platinum-Tin and Gold-Tin Bimetallic Particles Prepared from Solvated Metal Atoms.  Structure and Catalysis", in "Selectivity in Catalysis", ACS Symposium Series 517, Chapter 10, Mark E. Davis and Steven L. Suib, Editors, pp. 136-155 (1993).
  221. Klabunde, K.J. and Li, Y-X., "Clusters, Alloys, and Poisoning", in "Selectivity in Catalysis", ACS Symposium Series 517, Chapter 7, Mark E. Davis and Steven L. Suib, Editors, pp. 88-108, (1993).
  222. Glavee, G.N.; Klabunde, K.J.; Sorensen, C.M.; and Hadjipanayis, G.C., "Sodium Borohydride Reduction of Cobalt Ions in Nonaqueous Media.  Formation of Ultrafine Particles (Nanoscale) of Cobalt Metal", Inorganic Chemistry, 32, 474-477 (1993).
  223. Tang, Z.X.; Hadjipanayis, G.C.; Shah, S.I.; Papaefthymiou, V.; and Klabunde, K.J., "Preparation of Fe4N from Nd-containing Precursors", Journal of Magnetism and Magnetic Materials, 119, 49-53 (1993).
  224. Glavee, G.N.; Klabunde, K.J.; Sorensen, C.M.; and Hadjipanayis, G.C., "Borohydride Reduction of Cobalt Ions in Water.  Chemistry Leading to Nanoscale Metal, Boride, or Borate Particles", Langmuir, 9, 162-169 (1993).
  225. Itoh, H.; Utamapanya, S.; Stark, J.V.; Klabunde, K.J.; and Schlup, J.R., "Nanoscale Metal Oxide Particles as Chemical Reagents.  Intrinsic Effects of Particle Size on Hydroxyl Content and on Reactivity and Acid/Base Properties of Ultrafine Magnesium Oxide", Chem. Mater., 5, 71-77 (1993).
  226. Koper, O.; Li, Y-X.; and Klabunde, K.J., "Destructive Adsorption of Chlorinated Hydrocarbons on Ultrafine (Nanoscale) Particles of Calcium Oxide", Chem. Mater., 5, 500-505 (1993).
  227. Hooker, P.D. and Klabunde, K.J., "Reaction of Nickel Atoms with Molten Salts.  A New Approach to the Synthesis of Nanoscale Metal, Metal Oxide, and Metal Carbide Particles", Chem. Mater., 5, 1089-1093 (1993).
  228. Glavee, G.N.; Klabunde, K.J.; Sorensen, C.M.; Hadjipanayis, G.C.; Tang, Z.X.; Yiping, L.; "Preparation of Magnetic Fine Particles by Borohydride Reduction," Nanostructured Materials, 3, 391-398 (1993).
  229. Li, Q.; Sorensen, C.M.; Klabunde, K.J.; Hadjipanayis, G.C.; "Aerosol Spray Pyrolysis Synthesis of Magnetic Manganese Ferrite Particles," Aerosol Sci. Tech., 19, 453-467 (1993).
  230. Klabunde, K.J.; Stark, J.V.; Koper, O.; Mohs, C.; Khaleel, A.; Glavee, G.N.; Zhang, D.; Sorensen, C.M.; Hadjipanayis, G.C.; "Chemical Synthesis of Nanophase Materials", in "Nanophase Materials, Synthesis, Properties, and Applications", Hadjipanayis, G.C. and Siegel, R.W., editors, NATO ASI Series, Series E, Applied Sciences, Vol. 260, 1-19 (1994).  Kluwer Academic Publ., Dordrecht, Netherlands.  (Proceedings of NATO meeting, Corfu, Greece, June 1993.)
  231. Klabunde, K.J.; Li, Y-X.; Khaleel, A.; "Catalysis and Surface Chemistry: Metal Clusters/Nanoscale Particles", in "Nanophase Materials, Synthesis, Properties, and Applications", Hadjipanayis, G.C. and Siegel, R.W., editors, NATO ASI Series, Series E, Applied Sciences, Vol. 260, 757-769 (1994).  Kluwer Academic Publ., Dordrecht, Netherlands.  (Proceedings of NATO meeting, Corfu, Greece, June 1993.)
  232. Mohs, C.R.; Klabunde, K.J.; "Preparation of Small Particles of Titanium (IV) Oxide", in "Nanophase Materials, Synthesis, Properties, and Applications", Hadjipanayis, G.C. and Siegel, R.W., editors, NATO ASI Series, Series E, Applied Sciences, Vol. 260, 121-124 (1994).  Kluwer Academic Publ., Dordrecht, Netherlands.  (Proceedings of NATO meeting, Corfu, Greece, June 1993.)
  233. Li, Y-X.; Li, H.; Klabunde, K.J.; "Destructive Adsorption of Chlorinated Benzene on Ultrafine (Nanoscale) Particles of Magnesium Oxide and Calcium Oxide", in "Nanophase Materials, Synthesis, Properties, and Applications", Hadjipanayis, G.C. and Siegel, R.W., editors, NATO ASI Series, Series E, Applied Sciences, Vol. 260, 793-796 (1994).  Kluwer Academic Publ., Dordrecht, Netherlands.  (Proceedings of NATO meeting, Corfu, Greece, June 1993.)
  234. Stark, J.V.; Klabunde, K.J.; "Nanoscale Magnesium Oxide Used to Adsorb SO2 and CO2", in "Nanophase Materials, Synthesis, Properties, and Applications", Hadjipanayis, G.C. and Siegel, R.W., editors, NATO ASI Series, Series E, Applied Sciences, Vol. 260, 797-800 (1994).  Kluwer Academic Publ., Dordrecht, Netherlands.  (Proceedings of NATO meeting, Corfu, Greece, June 1993.)
  235. Khaleel, A.; Klabunde, K.J.; "Iron Oxide on Magnesium Oxide Support as a New Destructive Adsorbent for Chlorinated Hydrocarbons", in "Nanophase Materials, Synthesis, Properties, and Applications", Hadjipanayis, G.C. and Siegel, R.W., editors, NATO ASI Series, Series E, Applied Sciences, Vol. 260, 785-788 (1994).  Kluwer Academic Publ., Dordrecht, Netherlands. (Proceedings of NATO meeting, Corfu, Greece, June 1993.)
  236. Zhang, D.; Klabunde, K.J.; Sorensen, C.; "Synthesis and Characterization of Iron-Magnesium Bimetallic Particles", in "Nanophase Materials, Synthesis, Properties, and Applications", Hadjipanayis, G.C. and Siegel, R.W., editors, NATO ASI Series, Series E, Applied Sciences, Vol. 260, 89-92 (1994).  Kluwer Academic Publ., Dordrecht, Netherlands.  (Proceedings of NATO meeting, Corfu, Greece, June 1993.)
  237. Koper, O.; Klabunde, K.J.; "Comparison of Nanoscale Calcium Oxide Versus Commercial Calcium Oxide With Respect to Decomposition of Carbon Tetrachloride", in "Nanophase Materials, Synthesis, Properties, and Applications", Hadjipanayis, G.C. and Siegel, R.W., editors, NATO ASI Series, Series E, Applied Sciences, Vol. 260, 789-792 (1994).  Kluwer Academic Publ., Dordrecht, Netherlands.  (Proceedings of NATO meeting, Corfu, Greece, June 1993.)
  238. Gangopadhyay, S.; Hadjipanayis, G.C., Sorensen, C.M.; Klabunde, K.J., "Exchange Anisotropy in Oxide Passivated Cobalt Fine Particles," J. Appl. Phys., 73, 6964-6966 (1993).
  239. Asirvatham, V.S.; Yao, Z.; Klabunde, K.J.; Metal Atom Synthesis and Structure of (η6-Toluene) bis (trichlorosilyl) iron Dihydride: An Unuaual Iron (IV) Complex," J. Amer. Chem. Soc., 116, 5493-5494 (1994).
  240. Rabinovitch, B.; Horner, R.H.; Klabunde, K.J.; Hooker, P.; "A New Method for Gilding Silver. Use of Organic Gold Sols", Metalsmith, 14, 41-43 (1994).
  241. Easom, K.A.; Klabunde, K.J.; Sorensen, C.M.; Hadjipanayis, G.C.; "Nanoscale Magnetic Particles. New Methods to Surface Protected Metallic and Immiscible Bimetallic Clusters/Particles", Polyhedron, 13, 1197-1223 (1994).
  242. Klabunde, K.J.; Zhang, D.; Glavee, G.N.; Sorensen, C.M.; Hadjipanayis, G.C.; "Encapsulated Nanoparticles of Iron Metal", Chem. of Materials, 6, 784-787 (1994).
  243. Li, Y-X.; Li, H.; Klabunde, K.J.; "Destructive Adsorption of Chlorinated Benzenes on Ultrafine (Nanoscale) Particles of Magnesium Oxide and Calcium Oxide", Env. Sci. Tech., 28, 1248-1253 (1994).
  244. Hooker, P.D.; Klabunde, K.J.; "Destructive Adsorption of Carbon Tetrachloride on Iron (III) Oxide", Env. Sci. Tech., 28, 1243-1247 (1994).
  245. Klabunde, K.J.; "Free Atoms, Clusters, and Nanoscale Particles", Academic Press, San Diego, CA, 1994. (311 page monograph.)
  246. Zhanpeisov, N.U.; Zhidomirov, G.M.; Yudanov, I.V.; Klabunde, K.J.; "Cluster Quantum Chemical Study of the Interaction of Dimethyl Methylphosphonate with Magnesium Oxide," J. Phys. Chem., 98, 10032-10035 (1994).
  247. Yiping, L.; Hadjipanayis, G.C., Sorensen, C.M.; Klabunde, K.J.; "Structural and Magnetic Properties of Ultrafine Fe-Pd Particles," J. Appl. Phys., 75, 5885-5887 (1994).
  248. Klabunde, K.J.; "Nanoscale Particles Destroy Toxic Substances," Centerpoint, 2 (1), 1-3 (1994); publ. by Hazardous Subst. Res. Centers of USA, Atlanta, Georgia (invited).
  249. Cardenas-Trivino, G.; Alvial, M.; Klabunde, K.J.; Pantoja-M, O; Soto-Z, H.; "Tin Colloids and Metal-Metal Oxide Films Prepared by Chemical Liquid Deposition. III," Colloid and Polymer Sci., 272, 310-316 (1994).
  250. Glavee, G.N.; Klabunde, K.J.; Sorensen, C.M.; Hadjipanayis, G.C.; 'Borohydride Reduction of Nickel and Copper Ions in Aqueous and Nonaqueous Media.  Controllable Chemistry Leading to Nanoscale Metal and Metal Boride Particles," Langmuir, 10, 4726-4730 (1994).
  251. Chen, J.P.; Lee, K.M.; Sorensen, C.M.; Klabunde, K.J.; Kadjipanayis, G.C.; "Magnetic Properties of Microemulsion Synthesized Cobalt Fine Particles," J. Appl. Phys. 75, 5876-5878 (1994).
  252. Li, Y.; Gong, W.; Hadjipanayis, G.C.; Sorensen, C.M.; Klabunde, K.J.; Papaefthymion; Kostikas, A.; Simopoulos, A.; "Size Effects on the Magntic Properties of Fine Fe-Cr Particles," J. Magn. Magn. Mater., 130, 261-266 (1994).
  253. Schmidt, E.; Klabunde, K.J.; "Metal Vapor Synthesis of Transition Metal Compounds," Encyclopedia of Inorganic Chem., King, R.B., editor; Wiley Intersciences, New York, N.Y., pg. 2196-2205, vol. 4 (1994). (invited chapter).
  254. Glavee, G.N.; Klabunde, K.J.; Sorensen, C.M.; Hadjipanayis, G.C.; "Chemistry of Borohydride Reduction of Iron (II) and Iron (III) Ions in Aqueous and Nonaqueous Media. Formation of Nanoscale Fe, FeB, and Fe2B Powders. Inorg. Chem. 34, 28-35 (1995).
  255. Jagirdar, B.R.; Klabunde, K.J.; "Mono-η6-Arene Complexes of Chromium (II) and Chromium (0). Arene Exchange and Arene Displacement Reactions of η6-Fluoroarene-Dicarbonylbis (Trichlorosilyl) and Tricarbonylchromium Derivatives. J. Coord. Chem. 34, 31-43 (1995).
  256. O'Brian, R.J.; Xu, L.; Milburn, D.R.; Li, Y.X.; Klabunde, K.J.; Davis, B.H.; "Fischer-Tropsch Synthesis: Impact of Potassium and Zirconium Promotors on the Activity and Structure of an Ultrafine Iron Oxide Catalyst," Topics in Catal., 2, 1-15 (1995).
  257. Chen, J.P.; Sorensen, C.M.; Klabunde, K.J.; Hadjipanaysis, G.C.; "Enhanced Magnetization of Nanoscale Colloidal Metal Particles," Phys. Rev. B., 51, 11527-11532 (1995).
  258. Koper, O.B.; Wovchko, E.A.; Glass, J.A.; Yates, J.T., Jr.; Klabunde, K.J.; "Decomposition of CCl4 on CaO," Langmuir, 11, 2054-2059 (1995).
  259. Yao, Z.; Klabunde, K.J.; Asirvatham, A.S.; "Unusual Iron (IV) Complexes: Metal Atom Synthesis and Studies of (η6-arene) Fe(H)2(SiCl3)2 (Arene = Benzene, Toluene, p-Xylene)," Inorgan. Chem., 34, 5289-5294 (1995).
  260. Klabunde, K.J.; Mahashwari, S.;with Science writer, Gruber, W., "Ultrafine Metal Oxides Dismantle Chlorinated Organics, Env. Eng. World, July/August, 36-37 (1995) (invited article in trade magazine).
  261. Klabunde, K.J.; Li, Y.X.; Khaleel, A.; "Building Heterogeneous Catalysts One Atom at a Time," Trans. of Kansas Acad. Sci., 98, 24-33 (1995) (invited paper for symposium on catalysis).
  262. Klabunde, K.J.; Khaleel, A.; Park, D.; "Overlayer of Iron Oxide on Nanoscale Magnesium Oxide Crystallites.  Chlorocarbon Destruction by Catalytic Solid State Ion-Ion Exchange at 400°C," High Temp. and Materials Science, 33, 99-106 (1995).
  263. Boronina, T.; Klabunde, K.J.; Sergeev, G.; "Destruction of Organoholides in Water Using Metal Particles: Carbon Tetrachloride/Water Reactions with Magnesium, Tin, and Zinc," Env. Sci. Tech., 29, 1511-1517 (1995).
  264. Klabunde, K.J.; Boronina, T.; with science writer; "Scrubbing Groundwater with Metal Cuts the Contaminants," Chemecology, 24 (7), 7 (1995).
  265. Yao, Z.; Klabunde, K.J.; "The First Trifluorosilyl Hydrido Transition Metal Compound: Metal Atom Synthesis and Structure of (η6-Toluene) bis (trifluorosilyl) iron Dihydride," Organometallics, 14, 5013-5014 (1995).
  266. Jagirdar, B.R.; Palmer, R.; Klabunde, K.J.; Radonovich, L.J.; "Metal Hydride vs Side-on σ-bonded Trichlorosilane Complexes of Arene-Chromium Derivatives: (η6-arene)Cr(CO)(H)2(SiCl3)2. Inorg. Chem. 34 278-283 (1995).
  267. Klabunde, K.J.; Cardenas-Trivino, G.; "Metal Atom/Vapor Approach to Active Metal Clusters/Particles," invited book chapter in "Active Metals. Preparation, Characterization, Applications, "Fürstner, A., editor, VCH Publ., Weinheim, Germany, Chap. 6, pg. 237-275 (1996).
  268. Klabunde, K.J.; Park, D.G.; Stark, J.V.; Koper, O.B.; Decker, S.; Jiang, Y.; Lagadic, I.; "Nanoscale Metal Oxides as Destructive Adsorbents.  New Surface Chemistry and Environmental Applications," NATO Advanced Study Institute, Pelizzetti, E., Editor, Kluwer Publ., Fine Particle Science and Technology, 691-706 (1996).
  269. Stark, J.V.; Park, D.G.; Lagadic, I.; Klabunde, K.J.; "Nanoscale Metal Oxide Particles/Clusters as Chemical Reagents. Unique Surface Chemistry on Magnesium Oxide as Shown by Enhanced Adsorption of Acid Gases (Sulfur Dioxide and Carbon Dioxide) and Pressure Dependence," Chem. Materials, 8, 1904-1912 (1996).
  270. Stark, J.V.; Klabunde, K.J.; "Nanoscale Metal Oxide Particles/Clusters as Chemical Reagents. Adsorption of Hydrogen Halides, Nitric Oxide and Sulfur Trioxide on Magnesium Oxide Nanocrystals and Compared with Microcrystals," Chem. Materials, 8, 1913-1918 (1996).
  271. Klabunde, K.J.; Stark, J.V.; Koper, O.; Mohs, C.; Park, D.G.; Decker, S.; Jiang, Y.; Lagadic, I.; Zhang, D.; "Nanocrystals as Stoichiometric Reagents with Unique Surface Chemistry," J. Phys. Chem., invited Feature Article, 100, 12142-12153 (1996).
  272. Khaleel, A.; Klabunde, K.J.; "Photochemical Synthesis of (η6-arene)Cr-hydridostannyl and (η-arene)Cr-bis-stannyl Complexes," Inorg. Chem., 35, 3223-3227, (1996).
  273. Klabunde, K.J.; "Metal Clusters (in Polymers, Synthesis and Characterization)," Polymeric Materials Encylopedia, Salamone, Joseph C., editor, CRC Press, Boca Raton, FL, pg. 4088-4094, (1996).
  274. Chen, J.P.; Sorensen, C.M.; Klabunde, K.J.; Hadjipanayis, G.C.; Devlin, E.; Kostikas, A.; "Size-Dependent Magnetic Properties of MnFe2O4 fine particles synthesized by coprecipitation,"Phys. Review B, 54, 9288-9296, (1996).
  275. Hadjipanayis, G.C.; Klabunde, K.J.; Sorensen, C.M.; "Magnetic and Structural Properties of Nanoparticles," invited book chapter in "Nanomaterials: Synthesis, Properties, and Applications," Edelstein, A.S.; Cammarata, R.C., editors, Inst. of Physics Publ., Bristol and Philadelphia, Chap. 15, 375-394 (1996).
  276. Jagirdar, B.R.; Klabunde, K.J.; Palmer, R.; Radonovich, L.J.; Williams, T.; "Mono-η6- Complexes of Chromium (II) and Chromium (0).  Electron Demanding Substituents, Structural, and Spectroscopic Data Comparisons," Inorg. Chimica Acta, 250, 317-326 (1996).
  277. Decker, S.; Klabunde, K.J.; "Enhancing Effect of Fe2O3 on the Ability of Nanocrystalline Calcium Oxide to Adsorb SO2," J. Amer. Chem. Soc., 118, 12465-12466 (1996).
  278. Boronina, T.; Klabunde, K.J.; Sergeev, G.; "Rebuttal to Comment on "Destruction of Organohalides in Water Using Metal Particles: Carbon Tetrachloride/Water Reactions with Magnesium, Tin, and Zinc," Env. Sci. Tech., 30, 3645 (1996).
  279. Cardenas-Trivino: Oliva, R.C.; Klabunde, K.J.; "Colloids and Films from Au, Ag, and Cu with Ethers," Eur. J. Solid State Inorg. Chem., 33, 1135-1147 (1996).
  280. Yiping, L.; Hadjipanayis, G.L.; Papaefthymiou, V.; Kostikas, A.; Simopoulos, A.; Sorensen, C.M.; Klabunde, K.J.; "Heat Treatment Effects on Structural and Magnetic Properties of Fine Fe-B Particles" J. Mag. Magnetic Mat., 164, 357-366, (1996).
  281. Zhang, D.; Glavee, G.; Klabunde, K.J.; Hadjipanayis, G.C.; Sorensen, C.M.; "Nanoscale Iron Crystallites Encapsulated in Nonmagnetic Metal Shells.  Synthesis, Chemical, and Magnetic Properties of Core/Shell Iron-Indium, Iron-Neodymium, and Related Materials, High Temp. Material Sci. (invited paper), 36, 93-115 (1996).
  282. Zhang, D.; Klabunde, K.J.; Sorensen, C.M.; Hadjipanayis, G.C.; "Synthesis of Nanoscale Magnetic Metal Particles Encapsulated in Magnesium Fluoride and the Properties of These Materials," High Temp. Material Sci., (invited paper), 36, 135-154 (1996).
  283. Yao, Z.; Klabunde, K.J.; Hupton, A.C.; "Metal Atom Synthesis and Studies of (π- Arene)Fe(IV) Complexes: (η6-Arene)Fe(H)2(SiRCl2) (Arene= Toluene, Benzene; R=H,Me)," Inorganica Chimica Acta, invited paper on Special Issue on Metal Hydride Compounds, 259, 119-124 (1997).
  284. Yao, Z.; Klabunde, K.J.; "The Strong Acidity and Deprotonation Process of (η6-Toluene) Fe(H)2(SiCl3)2," Inorg. Chem., 36, 2119-2123 (1997).
  285. Koper, O.; Lagadic, I.; Klabunde, K.J.; "Destructive Adsorption of Chlorinated Hydrocarbons on Ultrafine (Nanoscale) Particles of Calcium Oxide. 2.," Chem. Materials, 9, 838-848, (1997).
  286. Bedilo, A.; Klabunde, K.J.; "Synthesis of High Surface Area Zirconia Aerogels Using High Temperature Supercritical Drying," Nanostructured Materials (invited paper) 8, 119-135. (1997).
  287. Matsuhashi, H.; Klabunde, K.J.; "Electron-Donating Property of Sodium Metal-Doped Magnesium Oxide," Langmuir, 13, 2600-2602, (1997).
  288. Groshens, T.J.; Glavee, G.; Klabunde, K.J.; "2,2¢-Bipyridine (η6-Toluene) Iron (0)"; Synthetic Methods of Organometallic and Inorganic Chemsitry - Transition Metals, Part 2, Volume 8, Stuttgart, New York, Herrmann, W.A., Zybill, C.E., editors, Thieme Publ., pg. 196-197 (1997).
  289. Brezinski, M.M.; Klabunde, K.J.; Anderson, B.B.; "Bis (pentafluorophenyl) (η6 - toluene) cobalt (II)," invited paper in Synthetic Methods of Organometallic and Inorganic Chemistry - Transition Metals, Part 2, Volume 8, Herrmann, W.A., Zybill, C.E., editors, Thieme Publ., pg. 203-204, (1997).
  290. Choe, S.B.; Klabunde, K.J.; "(η6 - Toluene) bis (trichlorosilyl) nickel (II)," invited paper in Synthetic Methods of Organometallic and Inorganic Chemistry - Transition Metals, Part 2, Volume 8, Herrmann, W.A., Zybill, C.E., editors, Thieme Publ., pg. 219-221, (1997).
  291. Lin, S.T.; Klabunde, K.J.; "Bis (pentafluorophenyl) (η6 - Toluene) nickel (II)," invited paper in Synthetic Methods of Organometallic and Inorganic Chemistry - Transition Metals, Part 2, Volume 8, Herrmann, W.A., Zybill, C.E., editors, Thieme Publ., 221-223, (1997).
  292. Koper, O.B.; Klabunde, K.J.; "Destructive Adsorption of Chlorinated Hydrocarbons on Ultrafine (Nanoscale) Particles of Calcium Oxide.  3. Chloroform, Trichloroethene, and Tetrachloroethene," Chem. Materails, 9, 2481-2485 (1997)
  293. Koper, O.B.; Lagadic, I.; Volodin, A.; Klabunde, K.J.; "Alkaline-Earth Oxide Nanoparticles Obtained by Aerogel Methods.  Characterization and Rational for Unexpectedly High Surface Chemical Reactivities," Chem. Materials, 9, 2468-2480 (1997).
  294. Kim, H.J.; Kang, J.; Park. D.G.; Kweon, H.-J.; Klabunde, K.J.; "Effect of Core Morphology on the Decomposition of CCl4 over the Surface of Core/Shell Structured Fe2O3/MgO Composite Metal Oxides," Bull. Korean Chem. Soc., 18, 831-840 (1997).
  295. Klabunde, K.J.; Mohs, C.; "Nanoparticles and Nanostructural Materials" invited chapter for a book "Chemistry of Advanced Materials: An Overview," Interrante, L.; Hampden-Smith, M.; editors; Wiley - VCH, Inc., New York, Chap. 7, pg. 271 - 327 (1998).
  296. Boronina, T.N.; Lagadic, I.; Sergeev, G.; Klabunde, K. J.; "Activated and Non-Activated Forms of Zinc Powder.  Reactivity Towards Chlorocarbons in Water and AFM Studies of Surface Morphologies," Env. Sci., Tech., 32,  2614-2622 (1998)
  297. Decker, S.; Lagadic, I.; Klabunde, K.J.; Michalowicz, A.; Moscovici, J.; "EXAFS Observation of the Sr and Fe Site Structural Environment in SrO and Fe2O3-coated SrO Nanoparticles Used as Carbon Tetrachloride Destructive Adsorbents," Chem. Materials, 10, 674-678 (1998).
  298. Henriksen, M.; Klabunde, K.J.; Senning, A.; Sylvester-Hvid, K.O.; Mikkelsen, K.V.; Schultz, T.; Larsen, F. K.; Hazell, R. G.; "Synthesis of trans-(+)-1,2,3,3a,4a,6,7-Octaphenyl-3aH-4aH-dicyclopenta[b,e][1,4]dithiin by Dimerization and Further Rearrangement of the Transient 2,3,4,5-Tetraphenyl-2,4-cyclopentadiene-1-thione," Acta Chemica Scandinavica, 52, 950-957 (1998)
  299. Bedilo, A. F.; Klabunde, K.J.; "Synthesis of Catalytically Active Zirconia Aerogels," J. Catalysis, 176, 448-458 (1998).
  300. Tian, F.; Klabunde, K.J.; "Nonaqueous Gold Colloids.  Investigations of Deposition and Film Growth on Organically Modified Substrates, and Trapping of Molecular Gold Clusters with Alkyl Amine," New J. of Chemistry, invited paper to Special Issue on Nanoparticles/Technology, 1275-1283 (1998)
  301. Klabunde, K.J.; Khaleel, A.; "Iron Oxide Magnesium Oxide Composites and Method for Destruction of Chlorinated Hydrocarbon Using Such Composites," U.S. Patent 5,712,219 January 27, 1998.
  302. Jiang, Y.: Decker, S.; Mohs, C.;  and Klabunde, K.J., “ Catalytic Solid State Reactions on the Surface of Nanoscale Metal Oxide Particles,” J.Catalysis, 180, 24-35 (1998)
  303. Klabunde, K.J.; Khaleel, A., “Composite Metal Oxide Adsorbents,” U.S. Patent 5,759,939 June 2, 1998.
  304. Zhang, D.; Klabunde, K.J.; Sorensen, C.W.; “Magnetization Temperature Dependence in Iron Nanoparticles,” Phys. Rev. B., 58, 14167-14170 (1998).
  305. Lin, X.M.; Sorensen, C.M.; Klabunde, K.J.; Hadjipanayis, G.C.; “Temperature Dependence of Morphology and Magnetic Properties of Cobalt Nanoparticles Prepared by an Inverse Micelle Technique,” Langmuir, 14, 7140-7146 (1998).
  306. Li, W.;Klabunde, K.J.; "Ultrafine Zinc and Nickel, Palladium, Silver Coated Zinc Particles used for Reductive Dehalogenation of Chlorinated Ethylenes in Aqueous Solution," Croatica Chemica Acta, invited paper for Special Issue in Honor of Egon Matijevic", 71, 853-872 (1998).
  307. Klabunde, K.J.; Murphy, T.; “MgO, CaO, Used as Destructive Adsorbants,”: Fine Particle Technology News, Ritter, M.; editor, Vol.1, No.11, pg. 1-2, December 1998.    
  308. Boronina, T.N.;Dieken, L.; Lagadic, I.; Klabunde, K.J.; "Zinc-Silver, Zinc-Palladium, and Zinc-Gold as Active Bimetallic Systems for Carbon Tetrachloride Dechlorination in Water," J. Hazardous Substances Researc, http://www.engg.ksu.edu/HSRC/JHSR/v1_no6.html (on line) (1999).
  309. Khaleel, A.; Klabunde, K.J.; Johnson, A.; "Photochemical Synthesis of new (η6-Arene)Cr-Hydrido Stannyl and (η6-Arene)Cr-Bis-Stannyl Complexes.  Ligand Effects on the Sn‑H Interaction in the Hydrido Stannyl Compounds," J. Organomet. Chem., 572, 11-20 (1999).
  310. Lin, X.M.; Sorensen, C.M.; Klabunde, K.J.; Hadjipanayis, G.C.; “Control of Cobalt Nanoparticle Size by the Germ – Growth Method in Inverse Micelle System:  Size-Dependent Magnetic Properties,” J. Mater Res., 14, 1542-1547 (1999).
  311. Lucas, E.; Klabunde, K., “Nanocrystals as Destructive Adsorbents for Mimics of Chemical Warfare Agents,” Nanostructured Materials, 12, 179-182, (1999).
  312. Khaleel, A.; Lucas, E.; Pates, S.; Koper, O.B.; Klabunde, K.J.; “Nanocrystals as Adsorbents for Chemical Agents and Air Pollutants,” DOD Book Publication, in press.
  313. Khaleel, A.; Kapoor, P.; Klabunde, K.J.; “Nanocrystalline Metal Oxides as New Adsorbents for Air Purification,” Nanostructured Materials, 11, 459-468 (1999).
  314. Zhang, D.; Klabunde, K.J.; Sorensen, C.M.; Hadjipanayis, G.C. “Encapsulated Iron, Cobalt, and Nickel Nanocrystals; Effect of Coating Material (Mg, MgF2) on Magnetic Properties, “ Nanostructured Materials, 12, 1053-1058 (1999).
  315. Lin, X.M.; Sorensen, C.M.; Klabunde, K.J.; “Ligand-Induced Gold Nanocrystal Superlattice Formation in Colloid Solution,” Chem, of Materials, 11, 198-202 (1999).
  316. Sun, N.; Klabunde, K.J.; “Nanocrystal Metal Oxide-Chlorine Adducts:  Selective Catalysts for Chlorination of Alkanes,” J. Am. Chem. Soc., 121, 5587-5588 (1999).
  317. Lin, X. M.; Wang, G.M.; Sorensen, C.M.; Klabunde, K.J.; “Formation and Dissolution of Gold Nanocrystal Superlattices in a Colloidal Solution, J. Phys. Chem. B., 103, 5488-542 (1999).
  318. Klabunde, K.J.; Khaleel, A.; “Method for the Destruction of Unwanted Compounds Using Metal Oxide Composties,” U.S. Patent 5, 914, 436; June 22, 1999.
  319. Wagner, G.W.; Bartram, P.W.; Koper, O.; Klabunde, K.J.; “Reactions of VX, GD, and HD with Nanosize MgO,” J. Phys. Chem. B., 103, 3225-3228 (1999).
  320. Dragieva, I.; Stoynov, Z.; Klabunde, K.J.; “Boron Containing Nanoparticles and their Contribution to the Theory and Production of New Materials,” Nanostructured Materials, 12, 613-616 (1999).
  321. Sun N.; Klabunde, K.J.; “High Activity Solid Super Base Catalysts Employing Nanocrystals of Metal Oxides:  Isomerization and Alkylation Catalysis, Including Conversion of Propylene-Ethylene Mixtures to Pentenes and Heptenes,” J. Catalysis, 185, 506-512 (1999).
  322. Koper, O.; Lucas, E.; Klabunde, K.J.; “Development of Reactive Topical Skin Protectants Against Sulfur Mustard and Nerve Agents,” J. Appl. Toxicology, 19, S59-S70 (1999).
  323. Zhang, D.; Klabunde, K.J.; Sorensen, C.M.; Hadjipanayis, G.C.; “Size and Interface Dependent Magnetic Properties of Encapsulated Metal Clusters,” in Nano-Crystalline Thin Magnetic Oxides, Nedkov, I.; Ausloos, M., editors, Kluwer Academic Publ., NATO Science Series 3, High Technology, Vol. 72, p. 159-164 (1999).
  324. Krastev, V.; Stoimenov, P.; Stoeva, S.; Dragieva, I.; Klabunde, K.J.; “XPS Investigation of Oxidation State of CoBNH Nanoparticles,” in Nano-Crystalline Thin Metal Oxides, Nedkov, I.; Ausloos, M., editors, Kluwer Academic Publ., NATO Science Series 3, High Technology, Vol. 72, p. 301-308 (1999).
  325. Lin, X.M.; Wang, G.; Sorensen, C.M.; Klabunde, K.J.; “Thermal Blooming Effect on Particle Sizing with Photon Correlation Spectroscopy,” Applied Optics, 38, 1884-1886 (1999).
  326. Dragieva, I.; Stoeva, S.; Stoimenov, P.; Pavlikianiv, E.; Klabunde, K.J.; “Complex Formation in Solutions for Chemical Synthesis of Nanoscaled Particles Prepared by Borohydride Reduction Process,” Nanostructured Materials, 12, 267-270 (1999).
  327. Klabunde, K.J.; Decker, S.; Lucas, E.; Koper, O.; “How the Shape of Nanoparticles Affects their Adsorption Properties,” Cluster and Nanostructure Interfaces, 25-28, 577-582 (1999).
  328. Klabunde, K.J.; “Nanometer Sized Metal Oxide Particles for Ambient Temperature Adsorption of Toxic Chemicals,” U.S. Patent 5,990,373; November 23, 1999.
  329. Khaleel, A.; Lucas, E.; Pates, S.; Koper, O.; Klabunde, K.J.; “Nanocrystals as Absorbents for Chemical Agents and Air Pollutants,” Proc. ERDEC Sci. Conf. Chem. Biol. Def. Res., 323-329 (1999).
  330. Moscovici, J.; Michalowicz, A.; Decker, S.; Lagadic, I.; Latreche, K.; Klabunde, K.J.; “Alkaline Earth Oxide Nanoparticles as Destructive Absorbents for Environmental Toxins,” J. Synchrotron Radiat, 6, 604-606, (1999).
  331. Klabunde, K.J.; Dragieva, I.D.; Stoynov, Z.B.; Stoimenov, P.K.; Stoeva, S.I.; Ivanova, G.D.; Bliznakov, S.K.; “Nucleation, Growth, and Properties of Nanoparticles Produced by Borohydride Reduction,” Cluster and Nanostructure Interfaces, 25-28, 55-59 (2000).
  332. Koper, O; Klabunde, K.J.; “Nanoparticles for the Destructive Sorption of Biological and Chemical Contaminants,” U.S. Patent 6, 057, 488; May 2, 2000.
  333. Carnes, C.L.; Klabunde, K.J.; “Synthesis, Isolation, and Chemical Reactivity Studies of Nanocrystalline Zinc Oxide,” Langmuir, 16, 3764-3772 (2000).
  334. Richards, R.; Li, W.; Decker, S.; Davidson C.; Koper O.; Zaikovski V.; Volodin A.; Rieker T.; Klabunde K.J.; “Consolidation of Metal Oxide Nanocrystals.  Reactive Pellets with Controllable Pore Structure That Represent a New Family of Porous, Inorganic Materials,” J. Amer. Chem. Soc., 122, 4921-4925 (2000).
  335. Klabunde, K.J.; Koper, O.; Khaleel, A.; “Porous Pellet Adsorbents Fabricated From Nanocrystals,” U.S. Patent 6, 093, 236; July 25, 2000.
  336. Klabunde, K.J.; Sun, N.; “Dispersion and Stabilization of Reactive Atoms on the Surface of Metal Oxides,” U.S. Patent 6, 087, 294; July 11, 2000.
  337. Klabunde, K.J.; Zhang, D.; Sorensen, C.M.; “Encapsulated Nanometer Magnetic Particles,” U.S. Patent 6, 045, 925; April 4, 2000.
  338. Wagner, G.W.; Koper, O.B.; Lucas, E.; Decker, S.; Klabunde, K.J.; “Reactions of VX, GD, and HD with Nanosize CaO: Autocatalytic Dehydrohalogenation of HD,” J. Phys. Chem. B, 104, 5118-5123 (2000).
  339. Lin, X.M.; Sorensen, C.M.; Klabunde, K.J.; “Digestive Ripening Segregation and Superlattice Formation in Gold Nanocrystal Colloids,” J. Nano Research, 2, 157-164 (2000).
  340. Taketomi, S.; Sorensen, C.M.; Klabunde, K.J.; “Preparation of yttrium-iron-garnet nanocrystals dispersed in nanosize-pore glass,” J. Magnetism and Magn. Mat., 222, 54-64 (2000).
  341. Dragieva, I.D.; Klabunde, K.J.; Stoynov, Z.B.; Stoimenov, P.K.; Stoeva, S.I.; Ivanova, G.D.; Bliznakov, S.K.; “Nucleation, Growth, and Properties of Nanoparticles Produced by Borohydride Reduction,” in Cluster and Nanostructure Interfaces, Jena, P; Khanna, S.M.; Rao, B.K., editors; World Scientific Publishers, London, 55-59 (2000).
  342. Wagner, G.W.; Procell, L.R.; O’Connor, R.J.; Munavalli, S.; Carnes, C.L.; Kapoor, P.N.; Klabunde, K.J.; “Reactions of VX, GB, GD, and HD with Nanosize Al2O3.  Formation of Aluminophosphonates,” J.  Am Chem. Soc., 123, 1636-1644 (2001).
  343. Lin, X.M.; Jaeger, H.M.; Sorensen, C.M.; Klabunde, K.J.; “Formation of Long-Range-Ordered Nanocrystal Superlattices on Silicon Nitride Surfaces,” J. Phys. Chem. B., 105, 3353-3357 (2001).
  344. Klabunde, K.J., editor; “Nanoscale Materials in Chemistry, Wiley Interscience, New York, NY (2001).  Also, two chapters written for this book: Klabunde, K.J.; “Introduction to Nanotechnology,” Chap. 1, pgs 1-13; Klabunde, K.J.; Mulukutla, R.; “Chemical and Catalytic Aspects of Nanocrystals,” Chap. 7, pgs 223-261.
  345. Lucas, E.; Decker, S.; Khaleel, A.; Seitz, A.; Fultz, A.; Fultz, S.; Ponce, A.; Li, Wi; Carnes, C.; Klabunde, K.J.; “Nanocrystalline Metal Oxides as Unique Chemical Reagents/Sorbents,” Chem. Eur. J., 7<, 2505-2510 (2001).
  346. Fenelenov, V.B.; Melgunov, M.S.; Mishakov, I.V.; Richards, R.M.; Chesnekov, V.V; Volodin, A.M.; Klabunde, K.J.; “Changes in Texture and Catalytic Activity of Nanocrystalline MgO during its Transformation to MgCl2 in the Reaction with 1-Chlorobutane,” J. Phys. Chem. B., 105, 3937-3941 (2001).
  347. Dragieva, I.D.; Stoynov, Z.B.; Klabunde, K.J; “Synthesis of Nanoparticles by Borohydride Reduction and Other Applications,” Scripta Mater., 4, 2187-2191 (2001).
  348. Richards, R.M.; Mulukutla, R.S.; Mishakov, I.V.;  Chesnekov, V.; Volodin, A.M.; Zaikovski, V.; Sun, N.; Klabunde, K.J.; “Nanocrystalline Ultra High Surface Area Magnesium Oxide as a Selective Base Catalyst,” Scripta Mater., 4, 1663-1666 (2001).
  349. Stoeva, S.; Prasad, B.L.V.; Lin, X.M.; Klabunde, K.J.; Sorensen, C.M.; “Nanocrystal Superlattices of Thiolated Gold,” Am. Inst. Aeronautics and Astranautics, A01-42912, A1AA 2001-5026, pg. 748-755 (2001).
  350. Dang, Q.; Wen, G.; Sorensen, C.M.; Klabunde, K.J.; “Cadmium (Zinc) Manganese Sulfide Nanocrystalline (Cd1-xMnxS and Zn1-xMnxS) Dilute Magnetic Semiconductors. Synthesis, Annealing, and Effects of Surface Oxidation on Magnetic Properties,’ Israel J. Chem., 4, 63-68 (2001).
  351. Mosocovici, J.; Benzakour, M.; Decker, S.; Carnes, C.; Klabunde, K.J.; Michalowicz, A.; J. Synchrotron Radiat., 8, 925-927 (2001).
  352. Carnes, C.; Stipp, J., Klabunde, K.J.; “Synthesis, Characterization, and Adsorption Studies of Nanocrystalline Copper Oxide and Nickel Oxide,” Langmuir, 18, 1352-1359 (2002).
  353. Carnes, C.; Klabunde, K.J.; “Unique Chemical Reactivities of Nanocrystalline Metal Oxides toward Hydrogen Sulfide,” Chem. of Materials, 14, 1806-1811 (2002).
  354. Diao, Y.; Walawender, W.; Sorensen, C.; Klabunde, K.J.; Rieker, T.; “Hydrolysis of Magnesium Methoxide.  Effects of Toluene on Gel Structure and Gel Chemistry,” Chem. of Materials, 14, 362-368 (2002).
  355. Stoeva, S.; Klabunde, K.J.; Sorensen, C.; Dragieva, I.; “Gram-Scale Synthesis of Monodisperse Gold Colloids by the Solvated Metal Atom Dispersion Method and Digestive Ripening and Their Organization into Two- and Three-Dimensional Structures,” J. of American Chem. Society, 124, 2305-2311 (2002).
  356. Mishakov, I.; Bedilo, A.; Richards, R.; Chesnokov, V.; Volodin, A.; Zaikovskii, V.; Buyanov, R.; Klabunde, K.J.; “Nanocrystalline MgO as a Dehydrohalogenation Catalyst,” J. of Catalysis, 206, 40-48 (2002).
  357. Koper, O.; Klabunde, J.; Marchin, G.; Klabunde, K.J.; Stoimenov, P.; Bohra, L.; “Nanoscale Powders and Formulations with Biocidal Activity Toward Spores and Vegetative Cells of Bacillus Species, Viruses, and Toxins,” Current Microbiology, 44, 49-55 (2002).
  358. Decker, S.; Klabunde, J.S.; Khaleel, A.; Klabunde, K.J.; “Catalyzed Destructive Adsorption of Environmental Toxins with Nanocrystalline Metal Oxides.  Fluoro-, Chloro-, Bromocarbons, Sulfur, and Organophosphorus Compounds,” Environ. Sci. Tech., 36, 762-768 (2002).
  359. Olsen, A.; Klabunde, K.J.; “Metal Particles and Cluster Compounds,” Encyclopedia of Phys. Science and Tech., Academic Press, 3rd Edition, Volume 9, 513-550 (2002).
  360. Rajagopalan, S.; Koper, O.; Decker, S.; Klabunde, K.J.; “Nanocrystalline Metal Oxides as Destructive Adsorbents for Organophosphorus Compounds at Ambient Temperatures,” Chemistry, A European J., 8, 2602-2607 (2002).
  361. Carnes, C.L.; Kapoor, P.N.; Klabunde, K.J.; Bonevich, J.; “Synthesis Characterization and Adsorption Studies of Nanocrystalline Aluminum Oxide and a Bimetallic Nanocrystalline Aluminum Oxide/Magnesium Oxide,” Chem. Materials, 14, 2922-2929 (2002).
  362. Jeevanandam, P.; Klabunde, K.J.; “A Study on Adsorption of Surfactant Molecules on Magnesium Oxide Nanocrystals Prepared by an Aerogel Route.” Langmuir, 18, 5309-5313 (2002).
  363. Narske, R.M.; Klabunde, K.J.; Fultz, S.; “Solvent Effects on the Heterogeneous Adsorption and Reactions of (2-Chloroethyl) ethyl Sulfide on Nanocrystalline Magnesium Oxide,” Langmuir, 18, 4819-4825 (2002).
  364. Stoimenov, P.K.; Klinger, R.L.; Marchin, G.L.; Klabunde, K.J.; “Metal Oxide Nanoparticles as Bactericidal Agents,” Langmuir, 18, 6679-6686 (2002).
  365. Khaleel, A.; Klabunde, K.J.; “Characterization of Aerogel Prepared High-Surface-Area Alumina:  In Situ FTIR Study of Dehydroxylation and Pyridine Adsorption,” Chemistry, A European Journal, 8, 3991-3998 (2002). 
  366. Bedilo, A.F.; Sigel, M.J.; Koper, O.B. Melgunov, M.; Klabunde, K.J.; “Synthesis of Carbon-Coated MgO Nanoparticles,” J. Materials Research, 12, 3599-3604 (2002).
  367. Koper, O.B.; Klabunde, K.J.; Klabunde, J.S.; “Reactive Nanoparticles as Destructive Adsorbents For Biological and Chemical Contamination,” U.S. Patent 6,417,423 B1; July 9, 2002.
  368. Klabunde, K.J.; Khaleel, A.; “Metal Oxide Composites and Method For Destruction of Unwanted Fluids Using Such Composites,” European Patent EP 0,754,163 B1, November  6, 2002.
  369. Prasad, B.L.V.; Stoeva, S.I.; Sorensen, C.M.; Klabunde, K.J.; “Digestive Ripening of Thiolated Gold Nanoparticles:  The Effect of Alkyl Chain Length,” Langmuir, 18, 7515-7520 (2002).
  370. Medine, G.M.; Klabunde, K.J.; Zaikovski, V.; “Unusual Behavior of Nanocrystalline Strontium Oxide Toward Hydrogen Sulfide,” J. Nanoparticle Research, 4, 357-366 (2002).
  371. Hobson, S.; Braue, E.; Klabunde, K.; Koper, O.; Decker, S.; “Active Topical Skin Protectant Using Reactive Nanoparticles,” U.S. Patent 6,403,653, June 11, 2002.
  372. Hobson, S.; Braue, E.; Lehnert, E.; Klabunde, K.; Decker, S.; Hill, C.; Rhule, J.; Boring, E.; Koper, O.; “Active Topical Skin Protectants Using Combinations of Reactive Nanoparticles and Polyoxometalates or Metal Salts,” U.S. Patent 6,410,603, June 25, 2002.
  373. Carnes, C.L.; Klabunde, K.J.; “The Catalytic Methanol Synthesis over Nanoparticle Metal Oxide Catalysts,” J. Molecular Catal., 194, 227-236 (2003).
  374. Prasad, B.L.V.; Stoeva, S.I.; Sorensen, C.M.; Klabunde, K.J.; “Digestive-Ripening Agents for Gold Nanoparticles:  Alternatives to Thiols,” Chem. Materials, 15, 935-942 (2003).
  375. Choudary, B.M.; Mulukutla, R.S.; Klabunde, K.J.; “Benzylation of Aromatic Compounds with Different Crystallites of MgO,” J. Am. Chem. Soc., 125, 2020-2021 (2003).
  376. Melgunov, M.S.; Fenelonov, V.B.; Melgunova, E.A.; Bedilo, A.F.; Klabunde, K.J.; “Textural Changes during Topochemical Decomposition of Nanocrystalline Mg(OH)2 to MgO,” J. Phys. Chem., 107, 2427-2434 (2003).
  377. Kapoor, P.N.; Heroux, D.; Mulukutla, R.S.; Zaikovskii, V.; Klabunde, K. J.; “High Surface Area Homogeneous Nanocrystalline Bimetallic Oxides Obtained by Hydrolysis of Bimetallic μ-oxo Alkoxides,” J. Materials Chem., 13, 410-414 (2003).
  378. Stoeva, S.I., Prasad, B.L.V., Sitharaman, U., Stoimenov, P., Zaikovski, V., Sorensen, C.M., Klabunde, K.J., “Face-Centered Cubic and Hexagonal Close-Packed Nanocrystal Superlattices of Gold Nanoparticles Prepared by Different Methods,” J. Phys. Chem. B.   (invited paper for A. Henglein Special Issue), 107, 7441-7448 (2003).
  379. Prasad, B.L.V.; Stoeva, S.I.; Sorensen, C.M.; Zaikovski, V.; Klabunde, K.J.; “Gold Nanoparticles as Catalysts for Polymerization of Alkylsilanes to Siloxane Nanowires, Filaments, and Tubes,” J. Am. Chem. Soc., 125, 10488-10489 (2003).
  380. Jeevanandam, P.; Klabunde, K.J.; “Redispersion and Reactivity Studies on Surfactant-Coated Magnesium Oxide Nanoparticles,” Langmuir. 19, 5491-5495 (2003).
  381. Martyanov, Igor N.; Klabunde, K.J.; “Photocatalytic Oxidation of Gaseous 2-Chloroethyl Ethyl Sulfide over TiO2,” Environ. Sci. Technol., 37, 3448-3453 (2003)
  382. Chesnokov, V.V.; Bedilo, A.F.; Heroux, D.S.; Mishakov, I.V.; Klabunde, K.J.; “Oxidative Dehydrogenation of Butane over Nanocrystalline MgO, Al2O3, and VOx/MgO Catalysts in the Presence of Small Amounts of Iodine,” J. of Catalysis, 218, 438-446 (2003).
  383. Martyanov, I.N.; Savinov, E.N.; Klabunde, K.J.; “Influence of Solution Composition and Ultrasonic Treatment on Optical Spectra of TiO2 Aqueous Suspensions,” Journal of Colloid and Interface Science 267, 111-116 (2003).
  384. Stoimenov, P.K.; Zaikovski, V.; Klabunde, K.J.; “Novel Halogen and Interhalogen Adducts of Nanoscale Magnesium Oxide,” J. Am. Chem. Soc., 125, 12907-12913 (2003).
  385. Richards, R.M.; Volodin, A.M.; Bedilo, A.F.; Klabunde, K.J.; “ESR Study of Nanocrystalline Aerogel-Prepared Magnesium Oxide,” Phys. Chem. Chem. Phys., 5, 4229-4305 (2003).
  386. Klabunde, K.J.; “Nanometer Sized Metal Oxide Particles for Ambient Temperature Adsorbents of Toxic Chemicals,” Mexico Patent 991703, January 8, 2002.
  387. Klabunde, K.J.; Koper, O.; Khaleel, A.; “Pelotillas Adsorbentes, Porosas, Fabricadas A Partir De Nanocristales,” Mexico Patent 212293, December 18, 2002.
  388. Klabunde, K.J.; Stoeva, S.I.; Sorensen, C.M.; “Synthesis of Substantially Monodispersed Colloids,” U.S. Patent 6,562,403 B2, May 13, 2003.
  389. Prasad, B.L.V.; Stoeva, S.I.; Sorensen, C.M.; Zaikovski, V.; Klabunde, K.J.; “Gold Nanoparticles as Catalysts for Polymerization of Alkylsilanes to Form Siloxane Nanowires,” Patent Registration No. 26,262, Docket No. 34079-PRO, July 9, 2003.
  390. Takatomi, Susamu; Sorensen, Christopher M.; Klabunde, K.J.; “Calorimetric Study of Magnetic Fluids Under a Magnetic Field,” Physical Review E, 68, 021501-1 - 021501-8 (2003).
  391. Medine, Gavin M.; Zaikovskii, Vladimir; Klabunde, Kenneth J.; “Synthesis and Adsorption Properties of Intimately Intermingled Mixed Metal Oxide Nanoparticles,” J. Mater. Chem., 14, 757-763 (2004).
  392. Heroux, David S.; Volodin, Alexander M.; Zaikovski, Vladimir I.; Chesnokov, Vladimir V.; Bedilo, Alexander F.; Klabunde, Kenneth J.; “ESR and HRTEM Study of Carbon-Coated Nanocrystalline MgO,” J. Phys.Chem. B, 108, 3140-3144 (2004).
  393. Tenorio, Francisco J.; Murray, Ian; Martinez, Ana; Klabunde, Kenneth J.; Ortiz, J.V.; “Products of the Addition of Water Molecules to Al3O3¯ Clusters: Structure, Bonding, and Electron Binding Energies in Al3O4H2¯, Al3O5H4¯, Al3O4H2, and Al3O5H4,” J. Chem. Physics, 120, 7955-7962 (2004).
  394. Martyanov, Igor N.; Klabunde, Kenneth J.; “Decomposition of CCl3F over Vanadium Oxides and [MgVxOy]MgO Shell/Core-Like Particles,” J. Catalysis, 224, 340-346 (2004).
  395. Rodrigues, Shalini; Uma, S.; Martyanov, Igor, N.; Klabunde, K.J.; “Visible Light Induced Photocatalytic Activity for Degradation of Acetaldehyde Using Transition Metal Incorporated Al-MCM-41 (Aluminum Doped Silica Zeolitic Material),” J. Photochemistry and Photobiology A: Chemistry, 165, 51-58 (2004).
  396. Wang, J.; Uma, S.; Klabunde, K.J.; “Visible Light Photocatalysis in Transition Metal Incorporated Titania-Silica Aerogels,” Applied Catalysis B: Environmental, 48, 151-154 (2004).
  397. Uma, Sitheraman, Rodrigues, Shalini; Martyanov, Igor N.; Klabunde, Kenneth J.; “Exploration of Photocatalytic Activities of Titanosilicate ETS-10 and Transition Metal Incorporated ETS-10,” Microporous and Mesoporous Materials, 67, 181-187 (2004).